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D8-Diethanolamine

Item number	676524
CAS	103691-51-6
Formula	C4H3D8NO2
Molecular weight	113,19 g/mol
Quantity	1X100MG
storage conditions	4 °C
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Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 27.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	D8-Diethanolamine
Catalog No.:	676524
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Skin irritation (Category 2), H315 Serious eye damage (Category 1), H318 Specific target organ toxicity - repeated exposure (Category 2), H373 Chronic aquatic toxicity (Category 3), H412 Classification according to EU Directives 67/548/EEC or 1999/45/EC Xn Harmful R22, R48/22 Xi Irritant R38, R41, R52/53
Label elements
Pictogram	GHS05 acid acid GHS07 exclam exclam GHS08 silhouete silhouete
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment. P280 Wear eye protection/ face protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Synonyms : Bis(2-hydroxyethyl)amine 2,2′-Iminodiethanol Formula : C4H11NO2 Molecular weight : 105,14 g/mol CAS-No. : 111-42-2 EC-No. : 203-868-0 Index-No. : 603-071-00-1 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Diethanolamine CAS-No. EC-No. Index-No. 111-42-2 203-868-0 603-071-00-1 Acute Tox. 4; Skin Irrit. 2; Eye Dam. 1; STOT RE 2; Aquatic Chronic 3; H302, H315, H318, H373, H412 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Diethanolamine CAS-No. EC-No. Index-No. 111-42-2 203-868-0 603-071-00-1 Xn, R22 - R38 - R41 - R48/22 - R52/53 <= 100 %
Formula	C4H3D8NO2
Molecular Weight (g/mol)	113.19
CAS-No.	103691-51-6
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information No data available
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Air sensitive. Storage class (TRGS 510): Combustible liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry Hands Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: colourless b) Odour ammoniacal c) Odour Threshold No data available d) pH 11,0 - 12 at 105 g/l at 25 °C e) Melting point/freezing point Melting point/range: 28 °C f) Initial boiling point and boiling range 217 °C at 200 hPa g) Flash point 138 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 10,6 %(V) Lower explosion limit: 1,6 %(V) k) Vapour pressure 1 hPa at 108 °C l) Vapour density 3,63 - (Air = 1.0) m) Relative density 1,097 g/mL at 25 °C n) Water solubility 105 g/l at 20 °C - completely soluble o) Partition coefficient: noctanol/ water log Pow: -2,18 p) Auto-ignition temperature 355 °C at 1.013 hPa q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Dissociation constant 8,92 at 23 °C Relative vapour density 3,63 - (Air = 1.0)
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability Absorbs carbon dioxide (CO2) from air. Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid No data available 10.5 Incompatible materials Oxidizing agents, Copper, Zinc, Iron 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male and female - 1.600 mg/kg (OECD Test Guideline 401) LD50 Dermal - Rabbit - 12.200 mg/kg LD50 Intraperitoneal - Rat - 120 mg/kg LD50 Intravenous - Rat - 778 mg/kg Skin corrosion/irritation No data available Serious eye damage/eye irritation Eyes - Rabbit Result: Risk of serious damage to eyes. (OECD Test Guideline 405) Respiratory or skin sensitisation Maximisation Test (GPMT) - Guinea pig Did not cause sensitisation on laboratory animals. (OECD Test Guideline 406) Germ cell mutagenicity Micronucleus test lymphocyte Result: negative Mutagenicity (micronucleus test) Mouse - male and female Result: negative Carcinogenicity IARC: 2B - Group 2B: Possibly carcinogenic to humans (Diethanolamine) Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information Repeated dose toxicity - Rat - male and female - Oral - Lowest observed adverse effect level - 25 mg/kg RTECS: KL2975000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Liver - Irregularities - Based on Human Evidence
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.460 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 30,1 mg/l - 48 h 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 93 % - Readily biodegradable (OECD Test Guideline 301F) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Harmful to aquatic life with long lasting effects. No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product
TRANSPORT INFORMATION	14.1 UN number ADR/RID: - IMDG: - IATA: - 14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods 14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: - 14.4 Packaging group ADR/RID: - IMDG: - IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!