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Tributyl phosphate

Item number677431
CAS126-73-8
FormulaC12H27O4P
Molecular weight266,31 g/mol
Quantity 1x1ml
storage conditions20 °C
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Tributyl phosphate

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 25.06.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Tributyl phosphate
Catalog No.:677431
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Carcinogenicity (Category 2), H351
Chronic aquatic toxicity (Category 3), H412
Label elements
PictogramGHS07 exclam
exclam
GHS08 silhouete
silhouete
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H315 Causes skin Irritation H351 Suspected of causing cancer.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
P273 Avoid release to the environment.
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you
feel unwell. Rinse mouth.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C12H27O4P
Molecular weight : 266,31 g/mol
CAS-No. : 126-73-8
EC-No. : 204-800-2
Index-No. : 015-014-00-2
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Tributyl phosphate
CAS-No.
EC-No.
Index-No.
126-73-8
204-800-2
015-014-00-2
Acute Tox. 4; Skin Irrit. 2;
Carc. 2; Aquatic Chronic 3;
H302, H315, H351, H412
<= 100 %
FormulaC12H27O4P
Molecular Weight (g/mol)266.31
CAS-No.126-73-8
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Oxides of phosphorus
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): Combustible liquids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: colourless
b) Odour odourless
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: -79
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents, Strong bases
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - 1.552 mg/kg
LC50 Inhalation - Rat - male and female - 4 h - > 4,242 mg/l
(OECD Test Guideline 403)
LD50 Dermal - Rabbit - > 3.100 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Irritating to Skin Serious eye damage/eye irritation
Eyes - Rabbit
Result: Mild eye irritation - 24 h
(OECD Test Guideline 405)
Respiratory or skin sensitisation
in vivo assay - Guinea pig
Result: Did not cause sensitisation on laboratory animals.
Germ cell mutagenicity
Chromosome aberration test in vitro
Chinese hamster ovary cells
Result: negative
Carcinogenicity
Carcinogenicity - Rat - Oral
Tumorigenic:Neoplastic by RTECS criteria. Kidney, Ureter, Bladder:Tumors.
Carcinogenicity - Mouse - Oral
Tumorigenic:Neoplastic by RTECS criteria. Liver:Tumors.
Limited evidence of carcinogenicity in animal studies
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - Rat - Oral
Effects on Newborn: Growth statistics (e.g., reduced weight gain).
Developmental Toxicity - Rat - Oral
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available Aspiration hazard
No data available
Additional Information
RTECS: TC7700000
CNS stimulation., To the best of our knowledge, the chemical, physical, and toxicological properties have
not been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish semi-static test LC50 - Oryzias latipes - 17 mg/l - 96 h
(OECD Test Guideline 203)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 89 % - Readily biodegradable
12.3 Bioaccumulative potential
Bioaccumulation Oryzias latipes - 38 d
- 93 μg/l
Bioconcentration factor (BCF): 21 - 35
12.4 Mobility in soil
No data available 12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Harmful to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 453/2010.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!