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Camphor

Item number685228
CAS76-22-2
FormulaC10H16O
Molecular weight152,23 g/mol
Quantity 1x100mg
storage conditions4 °C
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Camphor

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 04.12.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Camphor
Catalog No.:685228
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATIONAcute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
GHS08 silhouete
silhouete
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
Signal word Danger
Hazard statements
H228 Flammable solid.
H302+H332 Harmful if swallowed or if inhaled.
H370 Causes damage to organs.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

2.3 Other hazards
Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
COMPOSITION/INFORMATION ON INGREDIENTSChemical characterisation: Substances
CAS No. Description 76-22-2 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
Identification number(s) None
EC number: 200-945-0
RTECS: EX1225000
FormulaC10H16O
Molecular Weight (g/mol)152.23
CAS-No.76-22-2
FIRST AID MEASURES4.1 Description of first aid measures
General information:
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48 hours after the accident is recommended.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient in recovery position for transport.
Seek medical treatment.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing:
Rinse mouth. Do not induce vomiting.
Seek medical treatment.

4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.

4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
5.3 Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Avoid formation of dust.

6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.

6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.

6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
HANDLING AND STORAGE
EXPOSURE CONTROLS/PERSONAL PROTECTIONAdditional information about design of technical facilities: No further data; see item 7.

8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
76-22-2 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
WEL Short-term value: 19 mg/m³, 3 ppm
Long-term value: 13 mg/m³, 2 ppm
Additional information: Lists used were valid at the time of SDS preparation.

8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
Material of gloves Nitrile rubber, NBR
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection: Safety glasses
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Colour: White
Odour: Strong
Odour threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/freezing point: 176-179 °C
Initial boiling point and boiling range: 209 °C
Flash point: 66 °C
Flammability (solid, gas): Not determined.
Ignition temperature: 460 °C
Decomposition temperature: Not determined.
Auto-ignition temperature: Not determined.
Explosive properties: Product is not explosive. However, formation of explosive air/vapour mixtures is possible.
Explosion limits:
Lower: 0.6 Vol %
Upper: 4.5 Vol %
Vapour pressure: Not applicable.
Density at 20 °C: 1 g/cm³
Relative density Not determined.
Vapour density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with Chloroform, Ethyl acetate
water at 20 °C: 1.5 g/l
Partition coefficient: n-octanol/water: 2.38 logP
Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.

9.2 Other information No further relevant information available.
STABILITY AND REACTIVITY10.1 Reactivity Stable under normal conditions.

10.2 Chemical stability Stable under normal conditions.
Thermal decomposition / conditions to be avoided:
Formation of toxic gases is possible during heating or in case of fire.

10.3 Possibility of hazardous reactions Flammable.

10.4 Conditions to avoid
Sources of ignition
Heat.

10.5 Incompatible materials: Strong oxidizing agents.

10.6 Hazardous decomposition products:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
Harmful if swallowed or if inhaled.
LD/LC50 values relevant for classification:
Oral LD50 1,310 mg/kg (mouse)
LD 50 (Intraperitoneal) 3,000 mg/kg (mouse)
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure
Causes damage to organs.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
ECOLOGICAL INFORMATION12.1 Toxicity
Aquatic toxicity:
LC50/96 h 17 mg/l (fish)

12.2 Persistence and degradability No further relevant information available.

12.3 Bioaccumulative potential No further relevant information available.

12.4 Mobility in soil No further relevant information available.
Ecotoxicological effects:
Remark: Harmful to fish
Additional ecological information:
General notes:
Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water
Do not allow undiluted product to reach ground water, water course or sewage system.
Harmful to aquatic organisms

12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

12.6 Other adverse effects No further relevant information available.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
European waste catalogue
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.
Uncleaned packaging:
Recommendation: Dispose of in accordance with national regulations.
TRANSPORT INFORMATION14.1 UN-Number
ADR, IMDG, IATA UN2717
ADR 2717 CAMPHOR
IMDG, IATA CAMPHOR

14.3 Transport hazard class(es)
ADR, IMDG, IATA
Class 4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label 4.1

14.4 Packing group
ADR, IMDG, IATA III

14.5 Environmental hazards: Not applicable.

14.6 Special precautions for user Warning: Flammable solids, self-reactive substances and solid desensitised explosives.
Danger code (Kemler): 40
EMS Number: F-A,S-I
Stowage Category A

14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
Transport/Additional information:
ADR
Limited quantities (LQ) 5 kg
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
Transport category 3
Tunnel restriction code E
UN "Model Regulation": UN 2717 CAMPHOR, 4.1, III
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Directive 2012/18/EU
Named dangerous substances - ANNEX I Substance is not listed.
Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 40

15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!