|Molecular weight||152,23 g/mol|
|storage conditions||4 °C|
|CoA / MSDS||Retrieve CoA|
Show Safety Data Sheet online
|Safety Data Sheet||according to Regulation (EC) No 1907/2006 (REACH)|
Classifications according to Regulation (EC) No 1272/2008.
|IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING|
|Relevant identified uses of the substance or mixture||Identified: Laboratory chemical|
|Uses advised against:||HPC Standards GmbH|
Am Wieseneck 7
Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
|Emergency telephone number||HPC Standards Tel. +49 34291 3372-36 |
This number is only available during office hours.
|HAZARDS IDENTIFICATION||Acute Tox. 4 H302 Harmful if swallowed.|
Acute Tox. 4 H332 Harmful if inhaled.
|Labelling according to Regulation (EC) No 1272/2008|
The substance is classified and labelled according to the CLP regulation.
Signal word Danger
H228 Flammable solid.
H302+H332 Harmful if swallowed or if inhaled.
H370 Causes damage to organs.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
|COMPOSITION/INFORMATION ON INGREDIENTS||Chemical characterisation: Substances|
CAS No. Description 76-22-2 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
Identification number(s) None
EC number: 200-945-0
|Molecular Weight (g/mol)||152.23|
|FIRST AID MEASURES||4.1 Description of first aid measures|
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48 hours after the accident is recommended.
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient in recovery position for transport.
Seek medical treatment.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
Rinse mouth. Do not induce vomiting.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
|FIRE-FIGHTING MEASURES||5.1 Extinguishing media|
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
5.3 Advice for firefighters
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
|ACCIDENTAL RELEASE MEASURES||6.1 Personal precautions, protective equipment and emergency procedures|
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Avoid formation of dust.
6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
|HANDLING AND STORAGE|
|EXPOSURE CONTROLS/PERSONAL PROTECTION||Additional information about design of technical facilities: No further data; see item 7.|
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
WEL Short-term value: 19 mg/m³, 3 ppm
Long-term value: 13 mg/m³, 2 ppm
Additional information: Lists used were valid at the time of SDS preparation.
8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Material of gloves Nitrile rubber, NBR
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection: Safety glasses
|PHYSICAL AND CHEMICAL PROPERTIES||9.1 Information on basic physical and chemical properties|
Odour threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/freezing point: 176-179 °C
Initial boiling point and boiling range: 209 °C
Flash point: 66 °C
Flammability (solid, gas): Not determined.
Ignition temperature: 460 °C
Decomposition temperature: Not determined.
Auto-ignition temperature: Not determined.
Explosive properties: Product is not explosive. However, formation of explosive air/vapour mixtures is possible.
Lower: 0.6 Vol %
Upper: 4.5 Vol %
Vapour pressure: Not applicable.
Density at 20 °C: 1 g/cm³
Relative density Not determined.
Vapour density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with Chloroform, Ethyl acetate
water at 20 °C: 1.5 g/l
Partition coefficient: n-octanol/water: 2.38 logP
Dynamic: Not applicable.
Kinematic: Not applicable.
9.2 Other information No further relevant information available.
|STABILITY AND REACTIVITY||10.1 Reactivity Stable under normal conditions.|
10.2 Chemical stability Stable under normal conditions.
Thermal decomposition / conditions to be avoided:
Formation of toxic gases is possible during heating or in case of fire.
10.3 Possibility of hazardous reactions Flammable.
10.4 Conditions to avoid
Sources of ignition
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
|TOXICOLOGICAL INFORMATION||11.1 Information on toxicological effects|
Harmful if swallowed or if inhaled.
LD/LC50 values relevant for classification:
Oral LD50 1,310 mg/kg (mouse)
LD 50 (Intraperitoneal) 3,000 mg/kg (mouse)
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
Causes damage to organs.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
|ECOLOGICAL INFORMATION||12.1 Toxicity|
LC50/96 h 17 mg/l (fish)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Remark: Harmful to fish
Additional ecological information:
Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water
Do not allow undiluted product to reach ground water, water course or sewage system.
Harmful to aquatic organisms
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
|DISPOSAL CONSIDERATIONS||13.1 Waste treatment methods|
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
European waste catalogue
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.
Recommendation: Dispose of in accordance with national regulations.
|TRANSPORT INFORMATION||14.1 UN-Number|
ADR, IMDG, IATA UN2717
ADR 2717 CAMPHOR
IMDG, IATA CAMPHOR
14.3 Transport hazard class(es)
ADR, IMDG, IATA
Class 4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
14.4 Packing group
ADR, IMDG, IATA III
14.5 Environmental hazards: Not applicable.
14.6 Special precautions for user Warning: Flammable solids, self-reactive substances and solid desensitised explosives.
Danger code (Kemler): 40
EMS Number: F-A,S-I
Stowage Category A
14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
Limited quantities (LQ) 5 kg
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
Transport category 3
Tunnel restriction code E
UN "Model Regulation": UN 2717 CAMPHOR, 4.1, III
|REGULATORY INFORMATION||15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture|
Named dangerous substances - ANNEX I Substance is not listed.
Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 40
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
|OTHER INFORMATION||The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any|
guarantee of the properties of the product. For lab use only!