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Prothiofos

Item number674356
CAS34643-46-4
FormulaC11H15Cl2O2PS2
Molecular weight345,25 g/mol
Quantity 1X50MG
storage conditions4 °C
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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.07.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Prothiofos
Catalog No.:674356
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture
Regulation (EC) No 1272/2008
Acute toxicity - Oral Category 4 - (H302)
Acute toxicity - Inhalation (Dusts/Mists) Category 2 - (H330)
Skin sensitisation Category 1 - (H317)
Specific target organ toxicity — single exposure Category 2
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Label elements
PictogramGHS06 skull
skull
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word
Danger

Hazard statements
H302 - Harmful if swallowed
H317 - May cause an allergic skin reaction
H330 - Fatal if inhaled
H371 - May cause damage to organs
H410 - Very toxic to aquatic life with long lasting effects
Precautionary Statements - EU (28, 1272/2008)
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P310 - Immediately call a POISON CENTER or doctor
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
2.3. Other hazards
No information available.
COMPOSITION/INFORMATION ON INGREDIENTSClassification according to
Regulation (EC) No. 1272/2008
Acute Tox. 2 (H330)
Acute Tox. 4 (H302)
Skin Sens. 1 (H317)
STOT SE 2 (H371)
Aquatic Acute 1
(H400)
Aquatic Chronic 1
(H410)
FormulaC11H15Cl2O2PS2
Molecular Weight (g/mol)345.25
CAS-No.34643-46-4
FIRST AID MEASURES4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Inhalation If breathing has stopped, give artificial respiration. Get medical attention immediately.
Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device. If breathing is difficult, (trained personnel
should) give oxygen. IF exposed or concerned: Get medical advice/attention.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a doctor.
Skin contact: Wash with soap and water. May cause an allergic skin reaction. Wash off immediately with plenty of water for at least 15 minutes. If symptoms persist, call a doctor.
Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious
person. Call a doctor or poison control center immediately.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Do not breathe vapour or mist. Do
not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device. Use personal protective equipment as required. See section 8
for more information.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Coughing and/ or wheezing. Difficulty in breathing. Itching. Rashes. Hives.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically.
FIRE-FIGHTING MEASURES5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the
chemical
Product is or contains a sensitiser. May cause sensitisation by skin contact.
5.3. Advice for firefighters
Special protective equipment and
precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout
gear. Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Do not breathe
vapour or mist. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
HANDLING AND STORAGE7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not breathe vapour or mist. In case of insufficient ventilation, wear
suitable respiratory equipment. Handle product only in closed system or provide appropriate
exhaust ventilation. Do not eat, drink or smoke when using this product. Take off
contaminated clothing and wash it before reuse.
General hygiene considerations Do not breathe vapour or mist. Remove and wash contaminated clothing and gloves,
including the inside, before re-use. Contaminated work clothing should not be allowed out
of the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands
before breaks and after work. Wear suitable gloves and eye/face protection.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children. Store locked up. Please refer to the manufacturers certificate for specific
storage and transport temperature conditions. Store only in the original receptacle unless
other advice is given on the CoA.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
8.2. Exposure controls
Personal protective equipment
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles).

Hand protection Wear suitable gloves. The protective gloves to be used must comply with the specifications
of EC Directive 89/686/EEC and the related standard EN374. Wear protective
gloves.
Skin and body protection Wear suitable protective clothing.
Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.
General hygiene considerations Do not breathe vapour or mist. Remove and wash contaminated clothing and gloves,
including the inside, before re-use. Contaminated work clothing should not be allowed out
of the workplace. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands
before breaks and after work. Wear suitable gloves and eye/face protection.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties
Physical state Liquid
Appearance Liquid
Colour colourless
Odour Slight.
Odour threshold No information available
Property Values
Melting point / freezing point No data available
Initial boiling point and boiling
range
125 - 128 °C
Flammability No data available
Flammability Limit in Air
Upper flammability or explosive
limits
No data available
Lower flammability or explosive
limits
No data available
Flash point 194.4 °C
Autoignition temperature No data available
Decomposition temperature
pH No data available
pH (as aqueous solution) No data available
Kinematic viscosity No data available
Dynamic viscosity No data available
Water solubility No data available
Solubility(ies) No data available
Partition coefficient 4.92
Vapour pressure No data available
Relative density 1.3 at 20 °C
Bulk density No data available
Liquid Density No data available
Relative vapour density No data available
Particle characteristics
Particle Size No information available
Particle Size Distribution No information available
9.2. Information with regards to physical hazard classes
Not applicable
9.2.1. Other safety characteristics
No information available
STABILITY AND REACTIVITY10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
10.4. Conditions to avoid
Conditions to avoid Excessive heat.
10.5. Incompatible materials
Incompatible materials None known based on information supplied.
Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available. Fatal if inhaled. (based on
components).
Eye contact Specific test data for the substance or mixture is not available.
Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is
not available. Repeated or prolonged skin contact may cause allergic reactions with
susceptible persons. (based on components).
Ingestion Specific test data for the substance or mixture is not available. Harmful if swallowed. (based
on components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Coughing and/ or wheezing. Difficulty in breathing. Itching. Rashes. Hives.
Numerical measures of toxicity
Acute toxicity

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitisation May cause an allergic skin reaction.
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties
Endocrine disrupting properties No information available.
11.2.2. Other information
Other adverse effects No information available.
ECOLOGICAL INFORMATION12.1. Toxicity
Ecotoxicity Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.
12.4. Mobility in soil
Mobility in soil No information available.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB.
12.6. Endocrine disrupting properties
Endocrine disrupting properties No information available.
12.7. Other adverse effects
No information available.
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN2810
14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A3, A4, A137
ERG Code 6L
IMDG
14.1 UN number or ID number UN2810
14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II, Marine pollutant
14.5 Marine pollutant P
Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274
EmS-No F-A, S-A No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available
RID
14.1 UN number or ID number UN2810
14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II, Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T1
ADR
14.1 UN number or ID number UN2810
14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II, (D/E), Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T1
Tunnel restriction code (D/E)
REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Water hazard class (WGK) strongly hazardous to water (WGK 3)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work.
Authorizations and/or restrictions on use:
This product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This
product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors
Not applicable
Persistent Organic Pollutants
Not applicable
Dangerous substance category per Seveso Directive (2012/18/EU)
H2 - ACUTE TOXIC
E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Ozone-depleting substances (ODS) regulation (EC) 1005/2009
Not applicable
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!