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Prothiofos
| Item number | 674356 |
| CAS | 34643-46-4 |
| Formula | C11H15Cl2O2PS2 |
| Molecular weight | 345,25 g/mol |
| Quantity | 1X50MG |
| storage conditions | 4 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price |
|---|---|---|---|
Prothiofos | 673684 | 1X5ML | Please log in. |
674356 | 1X50MG | Please log in. | |
Prothiofos | 678104 | 1X1ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 27.07.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Prothiofos |
| Catalog No.: | 674356 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Acute toxicity - Oral Category 4 - (H302) Acute toxicity - Inhalation (Dusts/Mists) Category 2 - (H330) Skin sensitisation Category 1 - (H317) Specific target organ toxicity — single exposure Category 2 Acute aquatic toxicity Category 1 - (H400) Chronic aquatic toxicity Category 1 - (H410) |
| Label elements | |
| Pictogram | GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| Signal word Danger Hazard statements H302 - Harmful if swallowed H317 - May cause an allergic skin reaction H330 - Fatal if inhaled H371 - May cause damage to organs H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements - EU (28, 1272/2008) P260 - Do not breathe dust/fume/gas/mist/vapours/spray P273 - Avoid release to the environment P280 - Wear protective gloves P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P310 - Immediately call a POISON CENTER or doctor P391 - Collect spillage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed 2.3. Other hazards No information available. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | Classification according to Regulation (EC) No. 1272/2008 Acute Tox. 2 (H330) Acute Tox. 4 (H302) Skin Sens. 1 (H317) STOT SE 2 (H371) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) |
| Formula | C11H15Cl2O2PS2 |
| Molecular Weight (g/mol) | 345.25 |
| CAS-No. | 34643-46-4 |
| FIRST AID MEASURES | 4.1. Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Inhalation If breathing has stopped, give artificial respiration. Get medical attention immediately. Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen. IF exposed or concerned: Get medical advice/attention. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a doctor. Skin contact: Wash with soap and water. May cause an allergic skin reaction. Wash off immediately with plenty of water for at least 15 minutes. If symptoms persist, call a doctor. Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Call a doctor or poison control center immediately. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Do not breathe vapour or mist. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Use personal protective equipment as required. See section 8 for more information. 4.2. Most important symptoms and effects, both acute and delayed Symptoms Coughing and/ or wheezing. Difficulty in breathing. Itching. Rashes. Hives. 4.3. Indication of any immediate medical attention and special treatment needed Note to doctors May cause sensitisation in susceptible persons. Treat symptomatically. |
| FIRE-FIGHTING MEASURES | 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Large Fire CAUTION: Use of water spray when fighting fire may be inefficient. Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams. 5.2. Special hazards arising from the substance or mixture Specific hazards arising from the chemical Product is or contains a sensitiser. May cause sensitisation by skin contact. 5.3. Advice for firefighters Special protective equipment and precautions for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. |
| ACCIDENTAL RELEASE MEASURES | 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Avoid contact with skin, eyes or clothing. Do not breathe vapour or mist. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Other information Refer to protective measures listed in Sections 7 and 8. For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains. 6.3. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to other sections Reference to other sections See section 8 for more information. See section 13 for more information. |
| HANDLING AND STORAGE | 7.1. Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not breathe vapour or mist. In case of insufficient ventilation, wear suitable respiratory equipment. Handle product only in closed system or provide appropriate exhaust ventilation. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it before reuse. General hygiene considerations Do not breathe vapour or mist. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection. 7.2. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Store locked up. Please refer to the manufacturers certificate for specific storage and transport temperature conditions. Store only in the original receptacle unless other advice is given on the CoA. |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1. Control parameters Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. 8.2. Exposure controls Personal protective equipment Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles). Hand protection Wear suitable gloves. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374. Wear protective gloves. Skin and body protection Wear suitable protective clothing. Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. General hygiene considerations Do not breathe vapour or mist. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection. Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Liquid Colour colourless Odour Slight. Odour threshold No information available Property Values Melting point / freezing point No data available Initial boiling point and boiling range 125 - 128 °C Flammability No data available Flammability Limit in Air Upper flammability or explosive limits No data available Lower flammability or explosive limits No data available Flash point 194.4 °C Autoignition temperature No data available Decomposition temperature pH No data available pH (as aqueous solution) No data available Kinematic viscosity No data available Dynamic viscosity No data available Water solubility No data available Solubility(ies) No data available Partition coefficient 4.92 Vapour pressure No data available Relative density 1.3 at 20 °C Bulk density No data available Liquid Density No data available Relative vapour density No data available Particle characteristics Particle Size No information available Particle Size Distribution No information available 9.2. Information with regards to physical hazard classes Not applicable 9.2.1. Other safety characteristics No information available |
| STABILITY AND REACTIVITY | 10.1. Reactivity Reactivity No information available. 10.2. Chemical stability Stability Stable under normal conditions. Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None. 10.3. Possibility of hazardous reactions Possibility of hazardous reactions None under normal processing. 10.4. Conditions to avoid Conditions to avoid Excessive heat. 10.5. Incompatible materials Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. |
| TOXICOLOGICAL INFORMATION | 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Fatal if inhaled. (based on components). Eye contact Specific test data for the substance or mixture is not available. Skin contact May cause sensitisation by skin contact. Specific test data for the substance or mixture is not available. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. (based on components). Ingestion Specific test data for the substance or mixture is not available. Harmful if swallowed. (based on components). Symptoms related to the physical, chemical and toxicological characteristics Symptoms Coughing and/ or wheezing. Difficulty in breathing. Itching. Rashes. Hives. Numerical measures of toxicity Acute toxicity Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/eye irritation No information available. Respiratory or skin sensitisation May cause an allergic skin reaction. 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties Endocrine disrupting properties No information available. 11.2.2. Other information Other adverse effects No information available. |
| ECOLOGICAL INFORMATION | 12.1. Toxicity Ecotoxicity Very toxic to aquatic life with long lasting effects. 12.2. Persistence and degradability Persistence and degradability No information available. 12.3. Bioaccumulative potential Bioaccumulation There is no data for this product. 12.4. Mobility in soil Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB. 12.6. Endocrine disrupting properties Endocrine disrupting properties No information available. 12.7. Other adverse effects No information available. |
| DISPOSAL CONSIDERATIONS | 13.1. Waste treatment methods Waste from residues/unused products Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. Contaminated packaging Do not reuse empty containers. |
| TRANSPORT INFORMATION | IATA 14.1 UN number or ID number UN2810 14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group II Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II 14.5 Environmental hazards Yes 14.6 Special precautions for user Special Provisions A3, A4, A137 ERG Code 6L IMDG 14.1 UN number or ID number UN2810 14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group II Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II, Marine pollutant 14.5 Marine pollutant P Environmental hazards Yes 14.6 Special precautions for user Special Provisions 274 EmS-No F-A, S-A No information available 14.7 Maritime transport in bulk according to IMO instruments No information available RID 14.1 UN number or ID number UN2810 14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group II Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II, Environmentally Hazardous 14.5 Environmental hazards Yes 14.6 Special precautions for user Special Provisions 274, 614 Classification code T1 ADR 14.1 UN number or ID number UN2810 14.2 UN proper shipping name Toxic liquid, organic, n.o.s. (Prothiophos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group II Description UN2810, Toxic liquid, organic, n.o.s. (Prothiophos (ISO)), 6.1, II, (D/E), Environmentally Hazardous 14.5 Environmental hazards Yes 14.6 Special precautions for user Special Provisions 274, 614 Classification code T1 Tunnel restriction code (D/E) |
| REGULATORY INFORMATION | 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (WGK) strongly hazardous to water (WGK 3) European Union Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Authorizations and/or restrictions on use: This product does not contain substances subject to authorization (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII) DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors Not applicable Persistent Organic Pollutants Not applicable Dangerous substance category per Seveso Directive (2012/18/EU) H2 - ACUTE TOXIC E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1 Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |