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TCEP

Item number677433
CAS115-96-8
FormulaC6H12Cl3O4P
Molecular weight285,49 g/mol
Quantity 1x250mg
storage conditions20 °C
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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 25.06.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:TCEP
Catalog No.:677433
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Carcinogenicity (Category 2), H351
Reproductive toxicity (Category 1B), H360F
Chronic aquatic toxicity (Category 2), H411
Label elements
PictogramGHS07 exclam
exclam
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H302 Harmful if swallowed H351 Suspected of causing cancer.
H360F May damage fertility.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P281 Use personal protective equipment as required.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Supplemental Hazard
Statements
none
Restricted to professional users.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : Phosphoric acid tris(2-chloroethyl) ester
Formula : C6H12Cl3O4P
Molecular weight : 285,49 g/mol
CAS-No. : 115-96-8
EC-No. : 204-118-5
Index-No. : 015-102-00-0
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Tris(2-chloroethyl) phosphate Included in the Candidate List of Substances of Very High Concern
(SVHC) according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
Index-No.
115-96-8
204-118-5
015-102-00-0
Acute Tox. 4; Carc. 2; Repr.
1B; Aquatic Chronic 2; H302,
H351, H360F, H411
<= 100 %
FormulaC6H12Cl3O4P
Molecular Weight (g/mol)285.49
CAS-No.115-96-8
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11 4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
No data available
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation
of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry Hands Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Colour: colourless
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: ca.-59,99 °C - ASTM D 97-66
f) Initial boiling point and
boiling range
192 °C at 13 hPa
192 °C at 13 hPa
g) Flash point 232 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure < 13 hPa at 25 °C
l) Vapour density No data available
m) Relative density 1,39 g/cm3 at 25 °C
n) Water solubility 7.943 g/l at 20 °C - soluble
o) Partition coefficient: noctanol/
water
log Pow: 1,7 at 20 °C
p) Auto-ignition No data available temperature
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents, Strong bases
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Oxides of phosphorus,
Hydrogen chloride gas
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 1.150 mg/kg
(Directive 67/548/EEC, Annex V, B.1.)
LC50 Inhalation - Rat - 4 h - > 5 mg/l
LD50 Dermal - Rabbit - > 5.000 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Mild skin irritation
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
Respiratory or skin sensitisation
Buehler Test - Guinea pig
Did not cause sensitisation on laboratory animals.
Germ cell mutagenicity
in vitro assay
S. typhimurium
Result: negative Carcinogenicity
Limited evidence of carcinogenicity in animal studies
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Tris(2-chloroethyl)
phosphate)
Reproductive toxicity
Presumed human reproductive toxicant
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: KK2450000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to daphnia and
other aquatic
invertebrates
- Daphnia magna (Water flea) - ca. 170 mg/l - 48 h
(OECD Test Guideline 202)
Toxicity to algae - Pseudokirchneriella subcapitata - ca. 450 mg/l - 72 h
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 4 % - Not readily biodegradable.
(OECD Test Guideline 301C)
12.3 Bioaccumulative potential
Bioaccumulation Carassius auratus (goldfish) - 96 h
- 4 mg/l
Bioconcentration factor (BCF): 0,9
Cyprinus carpio (Carp) - 42 d
at 25 °C - 1 mg/l
Bioconcentration factor (BCF): 0,6 - 0,8
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Toxic to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal Company Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3082 IMDG: 3082 IATA: 3082
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tris(2-chloroethyl)
phosphate)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Tris(2-chloroethyl)
phosphate)
IATA: Environmentally hazardous substance, liquid, n.o.s. (Tris(2-chloroethyl) phosphate)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
14.6 Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Authorisations and/or restrictions on use
REACH - Restrictions on the manufacture, placing on
the market and use of certain dangerous substances,
preparations and articles (Annex XVII)
: Tris(2-chloroethyl) phosphate
REACH - Candidate List of Substances of Very High
Concern for Authorisation (Article 59).
: Tris(2-chloroethyl) phosphate
REACH - List of substances subject to authorisation
(Annex XIV)
: Tris(2-chloroethyl) phosphate
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!