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3-Methylbutyraldehyde

Item number688074
CAS590-86-3
FormulaC5H10O
Molecular weight86,13 g/mol
Quantity 1x250mg
storage conditions4 °C

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 02.12.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:3-Methylbutyraldehyde
Catalog No.:688074
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Eye irritation (Category 2), H319
Skin sensitisation (Category 1), H317
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Long-term (chronic) aquatic hazard (Category 2), H411
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 3-Methylbutanal
NSC 404119
Formula : C5H10O
Molecular weight : 86,13 g/mol
CAS-No. : 590-86-3
EC-No. : 209-691-5
Component Classification Concentration
Isovaleraldehyde
Flam. Liq. 2; Eye Irrit. 2;
Skin Sens. 1; STOT SE 3;
Aquatic Chronic 2; H225,
H319, H317, H335, H411
<= 100 %
FormulaC5H10O
Molecular Weight (g/mol)86.13
CAS-No.590-86-3
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Dry powder Dry sand
Unsuitable extinguishing media
Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13). 6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
Recommended storage temperature 2 - 8 °C
Handle and store under inert gas. Air and light sensitive.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Colour: colourless
b) Odour unpleasant
c) Odour Threshold No data available
d) pH No data available
e) Melting
point/freezing point
Freezing point: < -90 °C
f) Initial boiling point
and boiling range
91 - 93 °C at 1013 hPa
g) Flash point 0,5 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure 40 hPa at 20 °C
l) Vapour density 2,97 - (Air = 1.0)
m) Relative density 0,797 g/cm3
n) Water solubility 15 g/l at 20 °C - OECD Test Guideline 105 - soluble
o) Partition coefficient: log Pow: 1,5 at 25 °C n-octanol/water
p) Auto-ignition
temperature
210 °C
at 1.020 hPa
q) Decomposition
temperature
No data available
r) Viscosity 0,69 mm2/s at 20 °C -
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Relative vapour
density
2,97 - (Air = 1.0)
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Oxidizing agents, Strong bases, Strong reducing agents
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 5.600 mg/kg
Remarks: Behavioral:Somnolence (general depressed activity).
LD50 Oral - Rat - 5.740 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - 4 h - 42.700 mg/m3
Remarks: Behavioral:Altered sleep time (including change in righting reflex).
Gastrointestinal:Changes in structure or function of salivary glands.
LD50 Dermal - Rabbit - 2.534 mg/kg
Remarks: Liver:Other changes. Prolonged skin contact may cause skin irritation and/or
dermatitis.
Skin corrosion/irritation
Skin - Rabbit
Result: Mild skin irritation - 24 h Serious eye damage/eye irritation
Eyes - Rabbit
Result: Irritating to eyes. - 8 d
Respiratory or skin sensitisation
The preceding data, or interpretation of data, was determined using Quantitative Structure
Activity Relationship (QSAR) modeling.
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation. - Respiratory system
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: ES3450000
Nausea, Headache, Vomiting, To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 3,25 mg/l - 96 h
Toxicity to daphnia
and other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 177 mg/l - 48 h
Toxicity to algae ErC50 - Desmodesmus subspicatus (green algae) - 113 mg/l - 72 h
12.2 Persistence and degradability
Biodegradability Result: 50 % - Not readily biodegradable.
(OECD Test Guideline 301D)
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher 12.6 Other adverse effects
Toxic to aquatic life with long lasting effects.
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material
must be disposed of in accordance with the Directive on waste 2008/98/EC as well as
other national and local regulations. Leave chemicals in original containers. No mixing
with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 1989 IMDG: 1989 IATA: 1989
14.2 UN proper shipping name
ADR/RID: ALDEHYDES, N.O.S. (Isovaleraldehyde)
IMDG: ALDEHYDES, N.O.S. (Isovaleraldehyde)
IATA: Aldehydes, n.o.s. (Isovaleraldehyde)
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
:
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII) 15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!