Products

1-Butanol

Item number	678324
CAS	71-36-3
Formula	C4H10O
Molecular weight	74,12 g/mol
Quantity	1X5ML
storage conditions	20 °C
CoA / MSDS	Retrieve CoA Retrieve MSDS Show Safety Data Sheet online

Price

Please log in.

Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 19.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	1-Butanol
Catalog No.:	678324
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 4), H302 Skin irritation (Category 2), H315 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Label elements
Pictogram	flamme flamme GHS05 acid acid GHS07 exclam exclam
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H226 Flammable liquid and vapour. H302 Harmful if swallowed. H315 Causes skin Irritation H318 Causes serious eye damage. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear eye protection/ face protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P403 + P235 Store in a well-ventilated place. Keep cool. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Synonyms : Butyl alcohol n-Butanol Formula : C4H10O Molecular weight : 74,12 g/mol CAS-No. : 71-36-3 EC-No. : 200-751-6 Index-No. : 603-004-00-6 Registration number : 01-2119484630-38-XXXX Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration n-Butanol CAS-No. EC-No. Index-No. 71-36-3 200-751-6 603-004-00-6 Flam. Liq. 3; Acute Tox. 4; Skin Irrit. 2; Eye Dam. 1; STOT SE 3; H226, H302, H315, H318, H336, H335 <= 100 %
Formula	C4H10O
Molecular Weight (g/mol)	74.12
CAS-No.	71-36-3
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides Flash back possible over considerable distance. 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Handle and store under inert gas. hygroscopic Storage class (TRGS 510): Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Colour: colourless b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: -90 °C f) Initial boiling point and boiling range 116 - 118 °C g) Flash point 35 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 11,2 %(V) Lower explosion limit: 1,4 %(V) k) Vapour pressure 5 hPa at 20 °C l) Vapour density 2,56 - (Air = 1.0) m) Relative density 0,81 g/mL at 25 °C n) Water solubility soluble o) Partition coefficient: noctanol/ water No data available p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Relative vapour density 2,56 - (Air = 1.0)
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Exposure to moisture Heat, flames and sparks. 10.5 Incompatible materials Oxidizing agents, Alkali metals, Bases, Strong acids, Halogens 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 790 mg/kg Remarks: Liver:Fatty liver degeneration. Kidney, Ureter, Bladder:Other changes. Blood:Other changes. LC50 Inhalation - Rat - 4 h - 8000 ppm LD50 Dermal - Rabbit - 3.400 mg/kg Skin corrosion/irritation Skin - Rabbit Result: Skin irritation - 24 h Serious eye damage/eye irritation Eyes - Rabbit Result: Blindness (OECD Test Guideline 405) Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure May cause respiratory irritation. May cause drowsiness or dizziness. Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: EO1400000 drying, cracking of the skin, Skin irritation To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.840 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 1.983 mg/l - 48 h 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential Bioaccumulation Oncorhynchus mykiss (rainbow trout) - 24 h - 921 mg/l Bioconcentration factor (BCF): 0,38 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 1120 IMDG: 1120 IATA: 1120 14.2 UN proper shipping name ADR/RID: BUTANOLS IMDG: BUTANOLS IATA: Butanols 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	This safety datasheet complies with the requirements of Regulation (EC) No. 453/2010. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!