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Butyl acetate

Item number	681845
CAS	123-86-4
Formula	C6H12O2
Molecular weight	116,16 g/mol
Quantity	1X5ML
storage conditions	20 °C
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Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 25.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Butyl acetate
Catalog No.:	681845
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336
Label elements
Pictogram	flamme flamme GHS07 exclam exclam
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Warning Hazard statement(s) H226 Flammable liquid and vapour H336 May cause drowsiness or dizziness. Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Supplemental Hazard information (EU) EUH066 Repeated exposure may cause skin dryness or cracking. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Formula : C6H12O2 Molecular weight : 116,16 g/mol CAS-No. : 123-86-4 EC-No. : 204-658-1 Index-No. : 607-025-00-1 No components need to be disclosed according to the applicable regulations
Formula	C6H12O2
Molecular Weight (g/mol)	116.16
CAS-No.	123-86-4
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Dry powder Dry sand Unsuitable extinguishing media Do NOT use water jet. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: colourless, clear b) Odour fruity c) Odour Threshold No data available d) pH 6,2 at 5,3 g/l at 20 °C e) Melting point/freezing point Melting point/range: -78 °C - lit. f) Initial boiling point and boiling range 124 - 126 °C - lit. g) Flash point 27 °C - closed cup - Regulation (EC) No. 440/2008, Annex, A.9 h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 7,6 %(V) Lower explosion limit: 1,7 %(V) k) Vapour pressure 11,2 hPa at 20 °C - Regulation (EC) No. 440/2008, Annex, A.4 l) Vapour density 4,01 - (Air = 1.0) m) Relative density 0,88 g/mL at 25 °C - lit. n) Water solubility 5,3 g/l at 20 °C - OECD Test Guideline 105 - soluble o) Partition coefficient: n-octanol/water log Pow: 2,3 at 25 °C - OECD Test Guideline 117 - Bioaccumulation is not expected. p) Auto-ignition temperature 415 °C at 1.010 hPa - DIN 51794 q) Decomposition temperature No data available r) Viscosity 0,83 mm2/s at 20 °C - ASTM D 445 - 0,66 mm2/s at 40 °C - ASTM D 445 - s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Conductivity < 0,2 μS/cm Surface tension 61,3 mN/m at 1g/l at 20 °C - OECD Test Guideline 115 Relative vapour density 4,01 - (Air = 1.0)
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Strong oxidizing agents, Strong reducing agents, Strong bases 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - female - 10.760 mg/kg (OECD Test Guideline 423) LD50 Dermal - Rabbit - male and female - 14.112 mg/kg (OECD Test Guideline 402) Skin corrosion/irritation Skin - Rabbit Result: No skin irritation - 4 h (OECD Test Guideline 404) Drying-out effect resulting in rough and chapped skin. Serious eye damage/eye irritation Eyes - Rabbit Result: No eye irritation (OECD Test Guideline 405) Respiratory or skin sensitisation No data available Germ cell mutagenicity Ames test Escherichia coli/Salmonella typhimurium Result: negative OECD Test Guideline 474 Mouse - male and female - Red blood cells (erythrocytes) Result: negative Carcinogenicity This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure May cause drowsiness or dizziness. - Central nervous system Acute oral toxicity - Risk of aspiration upon vomiting., Aspiration may cause pulmonary oedema and pneumonitis. Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information Repeated dose toxicity - Rat - male and female - Oral - 13 Weeks - No observed adverse effect level - 125 mg/kg - Lowest observed adverse effect level - 500 mg/kg RTECS: AF7350000 Drowsiness To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After absorption of large quantities: somnolence, Drowsiness, narcosis Handle in accordance with good industrial hygiene and safety practice
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 18 mg/l - 96 h (OECD Test Guideline 203) Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 44 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 397 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) Toxicity to bacteria static test IC50 - Tetrahymena pyriformis - 356 mg/l - 40 h Remarks: (ECHA) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 83 % - Readily biodegradable. (OECD Test Guideline 301D) Theoretical oxygen demand 2.207 mg/g Remarks: (Lit.) Ratio BOD/ThBOD 7 - 46 % Remarks: (Lit.) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Harmful to aquatic life. Discharge into the environment must be avoided.
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 1123 IMDG: 1123 IATA: 1123 14.2 UN proper shipping name ADR/RID: BUTYL ACETATES IMDG: BUTYL ACETATES IATA: Butyl acetates 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. REACH - Restrictions on the manufacture, : placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!