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(-)-Menthone

Item number685677
CAS14073-97-3
FormulaC10H18O
Molecular weight154,25 g/mol
Quantity 1x5ml
storage conditions4 °C
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(-)-Menthone

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 02.12.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:(-)-Menthone
Catalog No.:685677
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Skin irritation (Category 2), H315
Skin sensitisation (Category 1), H317
Label elements
PictogramGHS07 exclam
exclam
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Warning Hazard statement(s)
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
Precautionary statement(s)
P280 Wear protective gloves.
P302 + P352 IF ON SKIN: Wash with plenty of water.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : (1R,4S)-p-Menthan-3-one
(2S,5R)-2-Isopropyl-5-methylcyclohexanone
Formula : C10H18O
Molecular weight : 154,25 g/mol
CAS-No. : 14073-97-3
EC-No. : 237-926-1
Component Classification Concentration
L-Menthan-3-one
Skin Irrit. 2; Skin Sens. 1;
H315, H317
<= 100 %
FormulaC10H18O
Molecular Weight (g/mol)154.25
CAS-No.14073-97-3
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13). Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Store in cool place. Recommended storage temperature 2 - 8 °C
Store under inert gas.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Colour: colourless b) Odour characteristic
c) Odour Threshold No data available
d) pH No data available
e) Melting
point/freezing point
Melting point/range: < -20 °C at 1.013 hPa - Regulation (EC)
No. 440/2008, Annex, A.1
f) Initial boiling point
and boiling range
207 - 210 °C - lit.
g) Flash point 74 °C - Regulation (EC) No. 440/2008, Annex, A.9
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure 0,8 hPa at 25 °C - OECD Test Guideline 104
l) Vapour density No data available
m) Relative density 0,893 g/cm3 at 20 °C - lit.
n) Water solubility 0,531 g/l at 20 °C - Regulation (EC) No. 440/2008, Annex, A.6 -
partly soluble
o) Partition coefficient:
n-octanol/water
log Pow: 3,05 at 25 °C - OECD Test Guideline 117 -
Bioaccumulation is not expected.
p) Auto-ignition
temperature
390 °C
at 1.008 - 1.012 hPa
q) Decomposition
temperature
No data available
r) Viscosity 1,9 mm2/s at 40 °C - OECD Test Guideline 114 - s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong oxidizing agents, Strong reducing agents 10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
No data available
Skin corrosion/irritation
Skin - In vitro study
Result: Irritating to skin. - 15 min
(OECD Test Guideline 439)
Remarks: (in analogy to similar products)
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
Local lymph node assay (LLNA) - Mouse
Result: positive
(OECD Test Guideline 429)
Germ cell mutagenicity
Ames test
Escherichia coli/Salmonella typhimurium
Result: negative
In vitro mammalian cell gene mutation test
Chinese hamster lung cells
Result: negative
OECD Test Guideline 474
Mouse - male and female - Bone marrow
Result: negative
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available Aspiration hazard
No data available
Additional Information
Repeated dose toxicity - Rat - male and female - Oral - 103 Weeks - No observed adverse
effect level - > 370 mg/kg
(in analogy to similar products)
RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish semi-static test LC50 - Danio rerio (zebra fish) - > 28 mg/l - 96 h
(OECD Test Guideline 203)
Remarks: (in analogy to similar products)
Toxicity to daphnia
and other aquatic
invertebrates
static test EC50 - Daphnia magna (Water flea) - ca. 30,6 mg/l - 48 h
(Regulation (EC) No. 440/2008, Annex, C.2)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 58 mg/l - 72 h
(OECD Test Guideline 201)
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
Harmful to aquatic life.
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material
must be disposed of in accordance with the Directive on waste 2008/98/EC as well as
other national and local regulations. Leave chemicals in original containers. No mixing
with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: - IMDG: - IATA: - 14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
:
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!