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2-Bromopropionic acid
| Item number | 690715 |
| CAS | 598-72-1 |
| Formula | C3H5BrO2 |
| Molecular weight | 152,97 g/mol |
| Quantity | 1X1ML |
| Concentration | 1000 µg/ml |
| Solvent | tert-Butyl methyl ether |
| storage conditions | 20 °C |
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| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 18.04.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | 2-Bromopropionic acid |
| Catalog No.: | 690715 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Skin irritation (Category 2), H315 Classification according to EU Directives 67/548/EEC or 1999/45/EC F Highly flammable R11 Xi Irritant R38 |
| Label elements | |
| Pictogram | flamme flamme GHS07 exclam exclam |
| Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. H315 Causes skin irritation. Precautionary statement(s) P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Supplemental Hazard Statements none 2.3 Other hazards - none | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : MTBE Methyl tert-butyl ether Formula : C5H12O Molecular weight : 88,15 g/mol CAS-No. : 1634-04-4 EC-No. : 216-653-1 Index-No. : 603-181-00-X Registration number : 01-2119452786-27-XXXX Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration tert-Butyl methyl ether CAS-No. EC-No. Index-No. 1634-04-4 216-653-1 603-181-00-X Flam. Liq. 2; Skin Irrit. 2; H225, H315 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration tert-Butyl methyl ether CAS-No. EC-No. Index-No. 1634-04-4 216-653-1 603-181-00-X F, Xi, R11 - R38 <= 100 % |
| Formula | C3H5BrO2 |
| Molecular Weight (g/mol) | 152.97 |
| CAS-No. | 598-72-1 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection impervious clothing, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point No data available f) Initial boiling point and boiling range 55 - 56 °C - lit. g) Flash point -33,0 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 15,1 %(V) Lower explosion limit: 1,6 %(V) k) Vapour pressure 1.018,7 hPa at 55,0 °C 279,2 hPa at 20,0 °C l) Vapour density No data available m) Relative density 0,74 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: noctanol/ water log Pow: 1,77log Pow: 0,94 p) Auto-ignition temperature 374,0 °C q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available |
| STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials Oxidizing agents, Strong acids 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 4.000 mg/kg LC50 Inhalation - Rat - 4 h - 23576 ppm Skin corrosion/irritation Skin - Rabbit Result: Skin irritation Serious eye damage/eye irritation Eyes - Rabbit Result: No eye irritation Respiratory or skin sensitisation Will not occur Germ cell mutagenicity No data available Carcinogenicity IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (tert-Butyl methyl ether) Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: KN5250000 Nausea, Vomiting, Dizziness, Central nervous system depression, Aspiration or inhalation may cause chemical pneumonitis., MTBE (methyl-tert-butyl ether) is reported to metabolize to tert-butyl alcohol and formaldehyde by microsomal demethylation, MTBE (methyl-tert-butyl ether) should be considered a "potential human carcinogen" due to an increase in leydig interstitial cell tumors of testes in male rats and an increase in lymphomas, leukemias, and uterine sarcomas in female rats., In another unpublished study MTBE was shown to be carcinogenic due to "increased incidence of a rare type of kidney tumor" in male rats and an "increase in the incidence of hepatocellular adenomas" in female mice., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Central nervous system - |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 672,00 mg/l - 96 h LC50 - other fish - > 1.000,00 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 472 mg/l - 48 h Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 491 mg/l - 96 h 12.2 Persistence and degradability Biodegradability Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301D) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects No data available |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2398 IMDG: 2398 IATA: 2398 14.2 UN proper shipping name ADR/RID: METHYL tert-BUTYL ETHER IMDG: METHYL tert-BUTYL ETHER IATA: Methyl tert-butyl ether 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available |
| REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |