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4-Vinyl-1-cyclohexene (stabilized)

Item number687852
CAS100-40-3
FormulaC8H12
Molecular weight108,18 g/mol
Quantity 1X1G
storage conditions20 °C
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4-Vinyl-1-cyclohexene (stabilized)

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 18.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:4-Vinyl-1-cyclohexene (stabilized)
Catalog No.:687852
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Skin irritation (Category 2), H315
Carcinogenicity (Category 2), H351
Reproductive toxicity (Category 2), H361
Aspiration hazard (Category 1), H304
Long-term (chronic) aquatic hazard (Category 3), H412
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
GHS08 silhouete
silhouete
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P273 Avoid release to the environment.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P331 Do NOT induce vomiting.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C8H12
Molecular weight : 108,18 g/mol
CAS-No. : 100-40-3
EC-No. : 202-848-9
Component Classification Concentration
4-vinylcyclohexene
Flam. Liq. 2; Skin Irrit. 2;
Carc. 2; Repr. 2; Asp. Tox.
1; Aquatic Chronic 3;
H225, H315, H351, H361,
H304, H412
<= 100 %
FormulaC8H12
Molecular Weight (g/mol)108.18
CAS-No.100-40-3
FIRST AID MEASURES4.1 Description of first-aid measures
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower. Consult a physician.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary
failure possible after aspiration of vomit. Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air at ambient temperatures.
Combustible.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
5.4 Further information
Remove container from danger zone and cool with water. Prevent fire extinguishing water
from contaminating surface water or the ground water system
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance
contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8. 6.2 Environmental precautions
Do not let product enter drains. Risk of explosion.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.
Chemizorb®). Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and
sources of ignition.
Recommended storage temperature 2 - 8 °C
Store under inert gas. Air sensitive. Packaged under inert gas.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Color: colorless
b) Odor unpleasant
c) Odor Threshold 0,0083 ppm
d) pH No data available
e) Melting
point/freezing point
Melting point/range: -101 °C - lit.
f) Initial boiling point
and boiling range
126 - 127 °C - lit.
g) Flash point 16 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapor pressure 15 hPa at 20 °C l) Vapor density 3,73 - (Air = 1.0)
m) Relative density 0,832 g/mL at 25 °C
n) Water solubility 0,05 g/l at 20 °C
o) Partition coefficient:
n-octanol/water
No data available
p) Autoignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity < 20 mm2/s at 400 °C -
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Relative vapor
density
3,73 - (Air = 1.0)
STABILITY AND REACTIVITY10.1 Reactivity
Vapors may form explosive mixture with air.
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Warming.
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 6.300 mg/kg
LD50 Dermal - Rabbit - 16.620 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Skin irritation
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye Irritation Respiratory or skin sensitization
No data available
Germ cell mutagenicity
Tests on bacterial or mammalian cell cultures did not show mutagenic effects.
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic
based on its IARC, ACGIH, NTP, or EPA classification.
Limited evidence of carcinogenicity in animal studies
IARC: 2B - Group 2B: Possibly carcinogenic to humans (4-vinylcyclohexene)
Reproductive toxicity
Suspected human reproductive toxicant
Specific target organ toxicity - single exposure
The substance or mixture is not classified as specific target organ toxicant, single exposure.
Specific target organ toxicity - repeated exposure
The substance or mixture is not classified as specific target organ toxicant, repeated
exposure.
Aspiration hazard
The substance or mixture is known to cause human aspiration toxicity hazards or has to be
regarded as if it causes a human aspiration toxicity hazard.
Additional Information
RTECS: GW6650000
Tremors, Nausea, Dizziness, Headache, To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Oryzias latipes - 17 mg/l - 48 h
12.2 Persistence and degradability
Biodegradability Result: - According to the results of tests of biodegradability this
product is not readily biodegradable.
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 1993 IMDG: 1993 IATA: 1993
14.2 UN proper shipping name
ADR/RID: FLAMMABLE LIQUID, N.O.S. (4-vinylcyclohexene)
IMDG: FLAMMABLE LIQUID, N.O.S. (4-vinylcyclohexene)
IATA: Flammable liquid, n.o.s. (4-vinylcyclohexene)
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
:
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
:
Other regulations
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or
stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!