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1,3-Dichloropropene

Item number	680179
CAS	542-75-6
Formula	C3H4Cl2
Molecular weight	110,97 g/mol
Quantity	1X250MG
storage conditions	20 °C
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Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 23.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	1,3-Dichloropropene
Catalog No.:	680179
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 3 H226 Flammable liquid and vapour. GHS06 skull and crossbones Acute Tox. 3 H301 Toxic if swallowed. Acute Tox. 3 H311 Toxic in contact with skin. Acute Tox. 3 H331 Toxic if inhaled. GHS08 health hazard Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. GHS09 environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation.
Label elements
Pictogram	flamme flamme GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red
	Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. · Hazard pictograms: GHS02 GHS06 GHS08 GHS09 · Signal word: Danger · Hazard statements: H226 Flammable liquid and vapour. H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H304 May be fatal if swallowed and enters airways. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements: P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable.
COMPOSITION/INFORMATION ON INGREDIENTS
Formula	C3H4Cl2
Molecular Weight (g/mol)	110.97
CAS-No.	542-75-6
FIRST AID MEASURES	4.1 Description of first aid measures · General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48 hours after the accident is recommended. In case of irregular breathing or respiratory arrest provide artificial respiration. · After inhalation: Supply fresh air and call a doctor. In case of unconsciousness place patient in recovery position for transport. Seek medical treatment in case of complaints. Take affected persons into fresh air and keep quiet. · After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth. Do not induce vomiting. Call a doctor immediately. Seek immediate medical advice. 4.2 Most important symptoms and effects, both acute and delayed: No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed: No further relevant information available.
FIRE-FIGHTING MEASURES	5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. 5.3 Advice for firefighters · Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device.
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures: Wear protective equipment. Keep unprotected persons away. 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation.
HANDLING AND STORAGE	7.1 Precautions for safe handling: Ensure good ventilation at the workplace. Store in cool, dry place in tightly closed receptacles. Information about fire and explosion protection: Keep ignition sources away, Do not smoke. Protect against electrostatic charges. 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. Please refer to the manufacturers certificate for specific storage and transport temperature conditions. Store only in the original receptacle unless other advice is given on the CoA. Keep container in a well ventilated place. Keep away from sources of ignition and heat. · Information about storage in one common storage facility: Store away from foodstuffs. · Further information about storage conditions: Keep container tightly sealed. 7.3 Specific end use(s) No further relevant information available.
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374. · Material of gloves: Fluorocarbon rubber (Viton) · Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties · Appearance Form: liquid · Odor: No data available · Odor Threshold: No data available · pH: No data available · Melting point/freezing point: Melting point/range: < -50 °C · Initial boiling point and boiling range: 97 - 112 °C - lit. · Flash point: 28 °C - closed cup · Evaporation rate: No data available · Flammability (solid,gas): No data available · Upper/lower flammability or explosive limits: No data available · Vapor pressure: No data available · Vapor density: No data available · Density: 1,198 g/cm3 at 25 °C - lit. Relative density: No data available · Water solubility: No data available · Partition coefficient n-octanol/water: No data available · Autoignition temperature: No data available · Decomposition temperature: No data available · Viscosity, kinematic: No data available Viscosity, dynamic: No data available ·Explosive properties: No data available · Oxidizing properties: No data available
STABILITY AND REACTIVITY	10.1 Reactivity Vapor/air-mixtures are explosive at intense warming. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature). 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heating. 10.5 Incompatible materials Metals, Strong oxidizing agents 10.6 Hazardous decomposition products In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity Acute toxicity estimate Oral - 100 mg/kg (Expert judgment) Acute toxicity estimate Oral - 100 mg/kg (Expert judgment) Acute toxicity estimate Inhalation - 4 h - 11 mg/l (Expert judgment) Acute toxicity estimate Inhalation - 4 h - 11 mg/l (Expert judgment) LD50 Dermal - Rabbit - 333 mg/kg Remarks: (RTECS) Skin corrosion/irritation Causes skin irritation. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Serious eye damage/eye irritation Causes serious eye irritation. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Respiratory or skin sensitization May cause allergic skin reaction. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive toxicity No data available Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation. - Respiratory Tract Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Specific target organ toxicity - repeated exposure No data available Aspiration hazard Aspiration may cause pulmonary edema and pneumonitis. 11.2 Additional Information RTECS: UC8310000 irritant effects, Effects due to ingestion may include:, Central nervous system depression. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 0,71 mg/l - 96,0 h Remarks: (ECOTOX Database) Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 0,09 mg/l - 48 h Remarks: (ECOTOX Database) 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. European waste catalogue Waste disposal key numbers from EWC have to be assigned depending on origin and processing. Uncleaned packaging: Recommendation: Dispose of in accordance with national regulations.
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 1992 IMDG: 1992 IATA: 1992 14.2 UN proper shipping name ADR/RID: FLAMMABLE LIQUID, TOXIC, N.O.S. (1,3- dichloropropene) IMDG: FLAMMABLE LIQUID, TOXIC, N.O.S. (1,3-Dichloropropene) IATA: Flammable liquid, toxic, n.o.s. (1,3-Dichloropropene) 14.3 Transport hazard class(es) ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA: 3 (6.1) 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out.
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!