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Ethiprole-sulfone
| Item number | 680245 |
| CAS | 120068-68-0 |
| Formula | C13H9Cl2F3N4O2S |
| Molecular weight | 413,20 g/mol |
| Quantity | 1x10mg |
| storage conditions | 4 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS Show Safety Data Sheet online |
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| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 24.09.2023 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Ethiprole-sulfone |
| Catalog No.: | 680245 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | · Classification of the substance or mixture GHS08 Health hazard STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS09 Environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. · Label elements · GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). |
| Label elements | |
| Pictogram | GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| · Label elements · GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). · Signal word Warning · Hazard statements H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray. P273 Avoid release to the environment. P314 Get medical advice/attention if you feel unwell. P391 Collect spillage. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Classification system: · NFPA ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0 · HMIS-ratings (scale 0 - 4) Health = 0 Fire = 0 Reactivity = 0 · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | · Chemical characterization: Substances · CAS No. Description 120068-68-0 Ethiprole-sulfone · Identification number(s) - · RTECS: - |
| Formula | C13H9Cl2F3N4O2S |
| Molecular Weight (g/mol) | 413.20 |
| CAS-No. | 120068-68-0 |
| FIRST AID MEASURES | · Description of first aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: Rinse mouth. Do not induce vomiting. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. |
| FIRE-FIGHTING MEASURES | · Extinguishing media · Suitable extinguishing agents: Use fire fighting measures that suit the environment. · Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. |
| ACCIDENTAL RELEASE MEASURES | · Personal precautions, protective equipment and emergency procedures Wear protective clothing. · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. · Protective Action Criteria for Chemicals · PAC-1: Substance is not listed. · PAC-2: Substance is not listed. · PAC-3: Substance is not listed. |
| HANDLING AND STORAGE | · Handling: · Precautions for safe handling Store in cool, dry place in tightly closed receptacles. · Information about protection against explosions and fires: No special measures required. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Please refer to the manufacturers certificate for specific storage and transport temperature conditions. Store only in the original receptacle unless other advice is given on the CoA. Keep container in a well-ventilated place. Keep away from sources of ignition and heat. · Information about storage in one common storage facility: Store away from foodstuffs. · Further information about storage conditions: None. · Specific end use(s) No further relevant information available. |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: Not required. · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Store protective clothing separately. · Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374 Protective gloves · Material of gloves Fluorocarbon rubber · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles |
| PHYSICAL AND CHEMICAL PROPERTIES | · Information on basic physical and chemical properties · General Information · Appearance: Form: Crystalline powder Color: White · Odor: Odorless · Odor threshold: Not determined. · pH-value: Not applicable. · Change in condition Melting point/Melting range: Not determined. Not determined. Boiling point/Boiling range: Not determined. · Flash point: Not applicable. · Flammability (solid, gaseous): Not determined. · Ignition temperature: Not determined · Decomposition temperature: Not determined. · Auto igniting: Not determined. · Danger of explosion: Not determined. · Explosion limits: Lower: Not determined. Upper: Not determined. · Vapor pressure: Not applicable. · Density: Not determined. · Relative density Not determined. · Vapor density Not applicable. · Evaporation rate Not applicable. · Solubility in / Miscibility with Water: Not determined. · Partition coefficient (n-octanol/water): 3.9 LogP · Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. · Other information No further relevant information available |
| STABILITY AND REACTIVITY | · Reactivity Stable under normal conditions. No further relevant information available. · Chemical stability Stable under normal conditions. · Thermal decomposition / conditions to be avoided: Formation of toxic gases is possible during heating or in case of fire. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid Heat. · Incompatible materials: Strong oxidizing agents. · Hazardous decomposition products: Formation of toxic gases is possible during heating or in case of fire. |
| TOXICOLOGICAL INFORMATION | · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: CAS: 181587-01-9 Ethiprole Oral LD50 >7,080 mg/kg (rat) Dermal LD50 >2,000 mg/kg (rat) Inhalative LC50/4 h >5.21 mg/l (rat) · Primary irritant effect: · on the skin: Based on available data, the classification criteria are not met. · on the eye: Based on available data, the classification criteria are not met. · Sensitization: Based on available data, the classification criteria are not met. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) Substance is not listed. · NTP (National Toxicology Program) Substance is not listed. · OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed. |
| ECOLOGICAL INFORMATION | · Toxicity · Aquatic toxicity: CAS: 181587-01-9 Ethiprole EC50/48 h >8.33 mg/l (daphnia) EC50/72h >16.4 mg/l (Algae) LC50/96 h 0.26 mg/l (fish) · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Ecotoxical effects: · Remark: Very toxic for fish · Additional ecological information: · General notes: Water hazard class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects No further relevant information available. |
| DISPOSAL CONSIDERATIONS | · Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Dispose in accordance with national regulations. |
| TRANSPORT INFORMATION | · UN-Number · DOT, ADR, IMDG, IATA UN3077 · DOT Environmentally hazardous substance, solid, n.o.s. (Ethiprole-sulfone) · ADR 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Ethiprole-sulfone) · IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Ethiprole-sulfone), MARINE POLLUTANT · IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Ethiprole-sulfone) · Transport hazard class(es) · DOT, ADR, IMDG, IATA · Class 9 Miscellaneous dangerous substances and articles · Label 9 · Packing group · DOT, ADR, IMDG, IATA III · Environmental hazards: · Marine pollutant: Yes (DOT) Symbol (fish and tree) · Special marking (ADR): Symbol (fish and tree) · Special marking (IATA): Symbol (fish and tree) · Special precautions for user Warning: Miscellaneous dangerous substances and articles · Danger code (Kemler): 90 · EMS Number: F-A,S-F · Stowage Category A · Stowage Code SW23 When transported in BK3 bulk container, see 7.6.2.12 and 7.7.3.9. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Remarks: Special marking with the symbol (fish and tree). · ADR · Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g · UN "Model Regulation": UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (ETHIPROLE-SULFONE), 9, III |
| REGULATORY INFORMATION | · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): Substance is not listed. · Section 313 (Specific toxic chemical listings): Substance is not listed. · TSCA (Toxic Substances Control Act): Substance is not listed. · Hazardous Air Pollutants Substance is not listed. · Proposition 65 · Chemicals known to cause cancer: Substance is not listed. · Chemicals known to cause reproductive toxicity for females: Substance is not listed. · Chemicals known to cause reproductive toxicity for males: Substance is not listed. · Chemicals known to cause developmental toxicity: Substance is not listed. · Carcinogenic categories · EPA (Environmental Protection Agency) Substance is not listed. · TLV (Threshold Limit Value established by ACGIH) Substance is not listed. · NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed. · Hazard pictograms GHS08 GHS09 · Signal word Warning · Hazard statements H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapors/spray. P273 Avoid release to the environment. P314 Get medical advice/attention if you feel unwell. P391 Collect spillage. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |