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Fenchlorphos

Item number	678223
CAS	299-84-3
Formula	C8H8Cl3O3PS
Molecular weight	321,55 g/mol
Quantity	1X100MG
storage conditions	-20 °C
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Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 19.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Fenchlorphos
Catalog No.:	678223
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1. Classification of the substance or mixture Regulation (EC) No 1272/2008 Acute toxicity - Oral Category 4 - (H302) Acute toxicity - Dermal Category 3 - (H311) Acute aquatic toxicity Category 1 - (H400) Chronic aquatic toxicity Category 1 - (H410)
Label elements
Pictogram	GHS06 skull skull GHS09 Aquatic-pollut-red Aquatic-pollut-red
	2.2. Label elements Signal word Danger Hazard statements H302 - Harmful if swallowed H311 - Toxic in contact with skin H410 - Very toxic to aquatic life with long lasting effects Precautionary Statements - EU (§28, 1272/2008) P264 - Wash face, hands and any exposed skin thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves and protective clothing P321 - Specific treatment (see supplemental first aid instructions on this label) P391 - Collect spillage P501 - Dispose of contents/ container to an approved waste disposal plant 2.3. Other hazards No information available. This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. Chemical name: Fenchlorphos EU - REACH (1907/2006) - Article 59(1) - Candidate List of Substances of Very High Concern (SVHC) for Authorisation: - EU - REACH (1907/2006) - Endocrine Disruptor Assessment List of Substances: -
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Chemical name: Fenchlorphos 299-84-3 Weight-%: 100 REACH registration number: - EC No: 206-082-6 Classification according to Regulation (EC) No. 1272/2008 [CLP]: Acute Tox. 3 (H311) Acute Tox. 4 (H302) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410) Specific concentration limit (SCL): M-Factor M-Factor (long-term) Acute Toxicity Estimate If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture based on its components Chemical name: Fenchlorphos 299-84-3 Oral LD50 mg/kg: 625 Dermal LD50 mg/kg: 1600 Inhalation LC50 - 4 hour - dust/mist - mg/L: No data available nhalation LC50 - 4 hour - vapour - mg/L: No data available Inhalation LC50 - 4 hour - gas - ppm: No data available This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59)
Formula	C8H8Cl3O3PS
Molecular Weight (g/mol)	321.55
CAS-No.	299-84-3
FIRST AID MEASURES	4.1. Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Inhalation Remove to fresh air. Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get immediate medical advice/attention. Ingestion Get immediate medical advice/attention. Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Self-protection of the first aider Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Wear personal protective clothing (see section 8). 4.2. Most important symptoms and effects, both acute and delayed Symptoms No information available. 4.3. Indication of any immediate medical attention and special treatment needed Note to doctors Treat symptomatically.
FIRE-FIGHTING MEASURES	5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Large Fire CAUTION: Use of water spray when fighting fire may be inefficient. Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams. 5.2. Special hazards arising from the substance or mixture Specific hazards arising from the chemical No information available. 5.3. Advice for firefighters Special protective equipment and precautions for fire-fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES	6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Other information Refer to protective measures listed in Sections 7 and 8. For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental precautions Environmental precautions Prevent further leakage or spillage if safe to do so. 6.3. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 6.4. Reference to other sections Reference to other sections See section 8 for more information. See section 13 for more information.
HANDLING AND STORAGE	7.1. Precautions for safe handling Advice on safe handling Take off contaminated clothing and wash it before reuse. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. General hygiene considerations Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage Conditions Please refer to the manufacturers certificate for specific storage and transport temperature conditions. Store only in the original receptacle unless other advice is given on the CoA. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Store locked up. 7.3. Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1. Control parameters Exposure Limits Chemical name: Fenchlorphos 299-84-3 European Union: - Austria: TWA: 5 mg/m3 STEL 10 mg/m3 H* Belgium: TWA: 5 mg/m3 TWA: 0.4 ppm Bulgaria: - Croatia: - Cyprus: - Czech Republic: - Denmark: TWA: 5 mg/m3 Estonia: - Finland: - France: TWA: 10 mg/m3 Germany: - Germany MAK: - Greece: TWA: 10 mg/m3 Hungary: - Ireland: TWA: 5 mg/m3 STEL: 15 mg/m3 Italy: - Italy REL: TWA: 5 mg/m3 Latvia: - Lithuania: - Luxembourg: - Malta: - Netherlands: - Norway: TWA: 5 mg/m3 STEL: 10 mg/m3 Poland: - Portugal: TWA: 5 mg/m3 Romania: - Slovakia: - Slovenia: - Spain: TWA: 5 mg/m3 Sweden: - Switzerland: TWA: 10 mg/m3 United Kingdom: - Biological occupational exposure limits Chemical name: Fenchlorphos 299-84-3 European Union: - Austria: - Bulgaria: 50 % of the reference value for the person - erythrocytes (Acetyl-cholinesterase) - at the end of exposure or end of work shift, for prolonged exposure - after several work shifts 30 % on the average for the group of exposed persons - erythrocytes (Acetyl-cholinesterase) - at the end of exposure or end of work shift, for prolonged exposure - after several work shifts Croatia: 30 % inhibition - blood (Acetyl cholinesterase activity) - at the end of the work shift 30 % inhibition - erythrocytes (Acetyl cholinesterase activity) - at the end of the work shift Czech Republic: - Denmark: - Finland: - France: 70 % of baseline - erythrocytes (Cholinesterase activity) - discretionary Germany: 70 % (erythrocytes - Acetylcholinesterase end of shift) 70 % (erythrocytes - Acetylcholinesterase for long-term exposures: at the end of the shift after several shifts) 70 % - BAT (end of exposure or end of shift) erythrocytes 70 % - BAT (for long-term exposures: at the end of the shift after several shifts) erythrocytes Germany: 70 % (erythrocytes - Acetylcholinesterase end of shift) 70 % (erythrocytes - Acetylcholinesterase for long-term exposures: at the end of the shift after several shifts) Hungary: - Ireland: 70 % of baseline (red blood cells - Cholinesterase activity discretionary) Italy: - Italy REL: 60 % of baseline - plasma (Butyrylcholinesterase activity) - end of shift 70 % of baseline - red blood cells (Cholinesterase activity) - discretionary Slovenia: - erythrocyte fraction of whole blood (Acetylcholinesterase) - at the end of the work shift; for long-term exposure: at the end of the work shift after several consecutive workdays Spain: 70 % of baseline (blood - Erythrocyte cholinesterase discretionary) Switzerland: - United Kingdom: - Derived No Effect Level (DNEL) No information available. Predicted No Effect Concentration (PNEC) No information available. 8.2. Exposure controls Personal protective equipment Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles). Hand protection Impervious gloves. Wear suitable gloves. The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374. Wear protective nitrile rubber or Viton™ gloves. Skin and body protection Wear suitable protective clothing. Chemical resistant apron. Long sleeved clothing. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water
PHYSICAL AND CHEMICAL PROPERTIES	9.1. Information on basic physical and chemical properties Physical state Solid Appearance Crystalline Colour off-white Odour No information available. Odour threshold No information available Property Values Remarks • Method Melting point / freezing point 41 °C None known Initial boiling point and boiling range97 °C None known Flammability No data available None known Flammability Limit in Air None known Upper flammability or explosive limits No data available Lower flammability or explosive limits No data available Flash point No data available None known Autoignition temperature No data available None known Decomposition temperature None known pH No data available None known pH (as aqueous solution) No data available No information available Kinematic viscosity No data available None known Dynamic viscosity No data available None known Water solubility No data available None known Solubility(ies) Acetone, Chloroform, Toluene Partition coefficient 4.88 None known Vapour pressure No data available None known Relative density 1.485 @ 25 °C Bulk density No data available Liquid Density No data available Relative vapour density No data available None known Particle characteristics Particle Size No information available Particle Size Distribution No information available 9.2. Other information Molecular weight 321.54 Molecular formula C8 H8 Cl3 O3 P S 9.2.1. Information with regards to physical hazard classes Not applicable 9.2.2. Other safety characteristics No information available
STABILITY AND REACTIVITY	10.1. Reactivity Reactivity No information available. 10.2. Chemical stability Stability Stable under normal conditions. Explosion data Sensitivity to mechanical impact None. Sensitivity to static discharge None. 10.3. Possibility of hazardous reactions Possibility of hazardous reactions None under normal processing. 10.4. Conditions to avoid Conditions to avoid None known based on information supplied. 10.5. Incompatible materials Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION	11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Information on likely routes of exposure Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Toxic in contact with skin. (based on components). Ingestion Specific test data for the substance or mixture is not available. Harmful if swallowed. (based on components). Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Numerical measures of toxicity Acute toxicity Component Information Chemical name: Fenchlorphos Oral LD50 = 625 mg/kg ( Rat ) Dermal LD50 = 1 gm/kg ( Rabbit ) Inhalation LC50 Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/eye irritation No information available. Respiratory or skin sensitisation No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration hazard No information available. 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties Endocrine disrupting properties 11.2.2. Other information Other adverse effects No information available.
ECOLOGICAL INFORMATION	12.1. Toxicity Ecotoxicity Very toxic to aquatic life with long lasting effects. Chemical name: Fenchlorphos Algae/aquatic plants: - Fish: LC50: 0.171 mg/l (Freshwater fish, 96h) Toxicity to microorganisms: - Crustacea: EC50: 0.0052 mg/l (Crustacean, 48h) 12.2. Persistence and degradability Persistence and degradability No information available. 12.3. Bioaccumulative potential Bioaccumulation There is no data for this product. Component Information Chemical name: Fenchlorphos Partition coefficient: 4.88 12.4. Mobility in soil Mobility in soil No information available. 12.5. Results of PBT and vPvB assessment PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB. 12.6. Endocrine disrupting properties Endocrine disrupting properties No information available. 12.7. Other adverse effects No information available.
DISPOSAL CONSIDERATIONS	13.1. Waste treatment methods Waste from residues/unused products Dispose of waste in accordance with environmental legislation. Dispose of in accordance with local regulations. Contaminated packaging Do not reuse empty containers.
TRANSPORT INFORMATION	IATA 14.1 UN number or ID number UN2783 14.2 UN proper shipping name Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group III Description UN2783, Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)), 6.1, III 14.5 Environmental hazards Yes 14.6 Special precautions for user Special Provisions A3, A5 ERG Code 6L IMDG 14.1 UN number or ID number UN2783 14.2 UN proper shipping name Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group III Description UN2783, Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)), 6.1, III, Marine pollutant 14.5 Marine pollutant P Environmental hazards Yes 14.6 Special precautions for user Special Provisions 61, 223, 274 EmS-No F-A, S-A No information available 14.7 Maritime transport in bulk according to IMO instruments No information available RID 14.1 UN number or ID number UN2783 14.2 UN proper shipping name Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group III Description UN2783, Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)), 6.1, III, Environmentally Hazardous 14.5 Environmental hazards Yes 14.6 Special precautions for user Special Provisions 61, 274, 648 Classification code T7 ADR 14.1 UN number or ID number UN2783 14.2 UN proper shipping name Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)) 14.3 Transport hazard class(es) 6.1 14.4 Packing group III Description UN2783, Organophosphorus pesticide, solid, toxic (Fenchlorphos (ISO)), 6.1, III, (E), Environmentally Hazardous 14.5 Environmental hazards Yes 14.6 Special precautions for user Special Provisions 61, 274, 648 Classification code T7 Tunnel restriction code (E)
REGULATORY INFORMATION	15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations France Occupational Illnesses (R-463-3, France) Chemical name: Fenchlorphos 299-84-3 French RG number: RG 34 Title: - Water hazard class (WGK) strongly hazardous to water (WGK 3) Poland SDS created according to the following Polish regulation: Act of February 25, 2011 on chemical substances and their mixtures (Journal of Laws of 2018, item 143, as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing the European Chemicals Agency (EC) as amended. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labeling and packaging of substances and mixtures, as amended. Regulation of the Minister of Health of 10 August 2012 on the criteria and method of classifying chemical substances and their mixtures (Journal of Laws of 2012, item 1018). Regulation of the Minister of Health of 20 April 2012 on labeling packaging of hazardous substances and mixtures and some mixtures (Journal of Laws of 2012, item 445). Regulation of the Minister of Family, Labor and Social Policy of 12 June 2018 on the maximum allowable concentrations and intensities of factors harmful to health in the work environment (Journal of Laws of 2018, item 1286). Announcement of the Minister of Economy, Labor and Social Policy of August 28, 2003 on the publication of the unified text of the Ordinance of the Minister of Labor and Social Policy on general health and safety at work regulations (Journal of Laws of 2003, No. 169, item 1650) . Regulation of the Minister of Health of 30 December 2004 on occupational safety and health related to the presence of chemical agents in the workplace (Journal of Laws of 2005, No. 11, item 86). Act of December 14, 2012 on waste (Journal of Laws of 2013, item 21) Regulation of the Minister of Health of December 30, 2004 on occupational health and safety related to the presence of chemical agents in the workplace (Journal U. of 2005, No. 11, item 86). Waste Act of December 14, 2012 (Journal of Laws of 2013, item 21). Act of 13 June 2013 on the management of packaging and packaging waste, Journal of Laws 2013, item 888). Government statement of September 24, 2002 - European Agreement on the International Carriage of Dangerous Goods by Road (ADR) (Journal of Laws No. 194, item 1629 and Journal of Laws of 2003, No. 207, item 2013 and 2014). European Union Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work. Authorisations and/or restrictions on use: This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII) DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors Not applicable Persistent Organic Pollutants Not applicable Dangerous substance category per Seveso Directive (2012/18/EU) E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1 Ozone-depleting substances (ODS) regulation (EC) 1005/2009 Not applicable International Inventories TSCA Contact supplier for inventory compliance status DSL/NDSL Contact supplier for inventory compliance status EINECS/ELINCS Contact supplier for inventory compliance status ENCS Contact supplier for inventory compliance status IECSC Contact supplier for inventory compliance status KECL Contact supplier for inventory compliance status PICCS Contact supplier for inventory compliance status AIIC Contact supplier for inventory compliance status Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances 15.2. Chemical safety assessment Chemical Safety Report A Chemical Safety Assessment is not required for this substance
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!