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Hexachloro-1,3-butadiene

Item number675348
CAS87-68-3
FormulaC4Cl6
Molecular weight260,76 g/mol
Quantity 1X250MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Hexachloro-1,3-butadiene

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13C4-Hexachloro-1,3-butadiene solution
Concentration: 100 µg/ml
Solvent: Acetone

686316
93951-70-3

1X1ML

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Hexachloro-1,3-butadiene

Hexachloro-1,3-butadiene

675348
87-68-3

1X250MG

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Hexachloro-1,3-butadiene solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Hexachloro-1,3-butadiene solution

686060
87-68-3

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 09.05.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Hexachloro-1,3-butadiene
Catalog No.:675348
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Dermal (Category 2), H310
Skin irritation (Category 2), H315
Serious eye damage (Category 1), H318
Carcinogenicity (Category 2), H351
Label elements
PictogramGHS05 acid
acid
GHS06 skull
skull
GHS08 silhouete
silhouete
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H301 Toxic if swallowed.
H310 Fatal in contact with Skin H315 Causes skin irritation.
H318 Causes serious eye damage.
H351 Suspected of causing cancer.
Precautionary statement(s)
P280 Wear protective gloves/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : Perchlorobutadiene
Formula : C4Cl6
Molecular weight : 260,76 g/mol
CAS-No. : 87-68-3
EC-No. : 201-765-5
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Hexachlorobuta-1,3-diene
CAS-No.
EC-No.
87-68-3
201-765-5
Acute Tox. 3; Acute Tox. 2;
Skin Irrit. 2; Eye Dam. 1; Carc.
2; H301, H310, H315, H318,
H351
<= 100 %
FormulaC4Cl6
Molecular Weight (g/mol)260.76
CAS-No.87-68-3
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11 4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas
Nature of decomposition products not known.
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Normal measures for preventive fire protection.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature 2 - 8 °C
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid, clear
Colour: light yellow
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: -22 - -19 °C - lit.
f) Initial boiling point and
boiling range
210 - 220 °C - lit. g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure 0,3 hPa at 20,0 °C
l) Vapour density No data available
m) Relative density 1,665 g/cm3 at 25 °C
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
No data available
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 82,0 mg/kg
LC50 Inhalation - Mouse - 370,0 mg/m3
LD50 Dermal - Rabbit - 100,0 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Skin irritation - 24 h Serious eye damage/eye irritation
Eyes - Rabbit
Result: Mild eye irritation - 24,00 h
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC, ACGIH, NTP, or EPA classification.
Limited evidence of carcinogenicity in animal studies
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Hexachlorobuta-1,3-diene)
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: EJ0700000
Liver injury may occur., Kidney injury may occur., Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx,
spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation,
Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting
Liver -
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish EC50 - Oncorhynchus mykiss (rainbow trout) - 0,14 mg/l - 96 h
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2279 IMDG: 2279 IATA: 2279
14.2 UN proper shipping name
ADR/RID: HEXACHLOROBUTADIENE
IMDG: HEXACHLOROBUTADIENE
IATA: Hexachlorobutadiene
14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: yes IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 453/2010.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Hexachlorobuta-1,3-diene CAS-No.: 87-68-3
Regulation (EC) No 850/2004 on Persistent Organic Pollutants - Annex I Substances Subject to
Prohibitions
Hexachlorobuta-1,3-diene CAS-No.: 87-68-3
Regulation (EC) No 850/2004 on Persistent Organic Pollutants - Annex IV Substances Subject to Waste
Management Provisions
Threshold limits : <= 100mg/kg
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!