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4-Methylphenol
| Item number | 677729 |
| CAS | 106-44-5 |
| Formula | C7H8O |
| Molecular weight | 108,14 g/mol |
| Quantity | 1X500MG |
| storage conditions | 20 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS Show Safety Data Sheet online |
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| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 20.04.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | 4-Methylphenol |
| Catalog No.: | 677729 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Dermal (Category 3) Acute toxicity, Oral (Category 3) Skin corrosion (Category 1B) Classification according to EU Directives 67/548/EEC or 1999/45/EC Toxic in contact with skin and if swallowed. Causes burns. |
| Label elements | |
| Pictogram | GHS05 acid acid GHS06 skull skull |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Danger Hazard statement(s) H301 Toxic if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. Precautionary statement(s) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazard Statements none According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R24/25 Toxic in contact with skin and if swallowed. R34 Causes burns. S-phrase(s) S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 2.3 Other hazards - none | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : p-Cresol 4-Methylphenol Formula : C7H8O Molecular Weight : 108,14 g/mol Component Concentration p-Cresol CAS-No. EC-No. Index-No. 106-44-5 203-398-6 604-004-00-9 - |
| Formula | C7H8O |
| Molecular Weight (g/mol) | 108.14 |
| CAS-No. | 106-44-5 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, laryngitis, Dizziness, Cardiovascular effects., Muscle cramps/spasms., Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. 4.3 Indication of any immediate medical attention and special treatment needed no data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information no data available |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13 |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. hygroscopic Air and light sensitive. Handle and store under inert gas. 7.3 Specific end uses no data available |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: crystalline Colour: colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range: 32 - 34 °C - lit. f) Initial boiling point and boiling range 202 °C - lit. g) Flash point 85,0 °C - closed cup h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits Lower explosion limit: 1,1 %(V) k) Vapour pressure 1,3 hPa at 20,0 °C l) Vapour density no data available m) Relative density 1,034 g/mL at 25 °C n) Water solubility no data available o) Partition coefficient: noctanol/ water log Pow: 1,94 p) Autoignition temperature 559,0 °C q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available 9.2 Other safety information no data available |
| STABILITY AND REACTIVITY | 10.1 Reactivity no data available 10.2 Chemical stability no data available 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Oxidizing agents, Bases 10.6 Hazardous decomposition products Other decomposition products - no data available |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 207,0 mg/kg Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Olfaction:Other changes. Behavioral:Convulsions or effect on seizure threshold. Gastrointestinal:Ulceration or bleeding from stomach. LC50 Inhalation - rat - 1 h - > 710 mg/m3 LD50 Dermal - rabbit - 301,0 mg/kg Remarks: Behavioral:Tremor. Gastrointestinal:Changes in structure or function of salivary glands. Kidney, Ureter, Bladder:Other changes. Skin corrosion/irritation Skin - rabbit - Severe skin irritation - 24 h Serious eye damage/eye irritation Eyes - rabbit - Severe eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation May be fatal if inhaled. May cause respiratory tract irritation. Ingestion Toxic if swallowed. Skin Toxic if absorbed through skin. May cause skin Irritation Eyes May cause eye irritation. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, laryngitis, Dizziness, Cardiovascular effects., Muscle cramps/spasms., Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Additional Information RTECS: GO6475000 |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - other fish - 16,00 - 24,00 mg/l - 24 h LC50 - Oncorhynchus mykiss (rainbow trout) - 7,9 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 1,4 mg/l - 48 h 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential Does not bioaccumulate. 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment no data available 12.6 Other adverse effects Toxic to aquatic life. no data available |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 3455 IMDG: 3455 IATA: 3455 14.2 UN proper shipping name ADR/RID: CRESOLS, SOLID IMDG: CRESOLS, SOLID IATA: Cresols, solid 14.3 Transport hazard class(es) ADR/RID: 6.1 (8) IMDG: 6.1 (8) IATA: 6.1 (8) 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user no data available |
| REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment no data available |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |