Trioctylamine

Item number	687309
CAS	1116-76-3
Formula	C24H51N
Molecular weight	353,67 g/mol
Quantity	1X1ML
storage conditions	4 °C
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Trioctylamine		687309 1116-76-3	1X1ML	Please log in.

Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 09.05.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Trioctylamine
Catalog No.:	687309
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Long-term (chronic) aquatic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16.
Label elements
Pictogram	GHS07 exclam exclam GHS09 Aquatic-pollut-red Aquatic-pollut-red
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal Word Warning Hazard statement(s) H315 Causes skin irritation. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Precautionary statement(s) P264 Wash skin thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/ attention. Supplemental Hazard Statements none Reduced Labeling (<= 125 ml) Pictogram Signal Word Warning Hazard statement(s) none Precautionary statement(s) none Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS	Substances Formula : C24H51N Molecular weight : 353,67 g/mol CAS-No. : 1116-76-3 EC-No. : 214-242-1 Component: trioctylamine, n- CAS-No. : 1116-76-3 Classification:Skin Irrit. 2; Eye Irrit. 2; Aquatic Chronic 2; H315, H319, H411 Concentration:<= 100 % For the full text of the H-Statements mentioned in this Section, see Section 16.
Formula	C24H51N
Molecular Weight (g/mol)	353.67
CAS-No.	1116-76-3
FIRST AID MEASURES	4.1 Description of first-aid measures General advice Show this material safety data sheet to the doctor in attendance. If inhaled After inhalation: fresh air. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. In case of eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Carbon dioxide (CO2) Foam Dry powder Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Carbon oxides Nitrogen oxides (NOx) Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. 5.3 Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. 5.4 Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Tightly closed. Storage class Storage class (TRGS 510): 10: Combustible liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 480 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 10 min Material tested:KCL 741 Dermatril® L Body Protection protective clothing Respiratory protection Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. Control of environmental exposure Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Physical state liquid b) Color No data available c) Odor No data available d) Melting point/freezing point Melting point: -34,6 °C e) Initial boiling point and boiling range 164 - 168 °C at 0,9 hPa - lit. 365 - 367 °C - lit. f) Flammability (solid, gas) No data available g) Upper/lower flammability or explosive limits No data available h) Flash point 168 °C - c.c. i) Autoignition temperature No data available j) Decomposition temperature No data available k) pH alkaline l) Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: 15 mPa.s at 20 °C m) Water solubility 0,0001 g/l at 25 °C n) Partition coefficient: n-octanol/water log Pow: 10,35 - A remarkable bioaccumulation potential is expected (log Po/w >3)., (Lit.) o) Vapor pressure < 0,01 hPa at 20 °C p) Density 0,809 g/cm3 at 25 °C - lit. Relative density No data available q) Relative vapor density No data available r) Particle characteristics No data available s) Explosive properties No data available t) Oxidizing properties none 9.2 Other safety information No data available
STABILITY AND REACTIVITY	10.1 Reactivity Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . 10.3 Possibility of hazardous reactions Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines! Violent reactions possible with: Strong oxidizing agents acid halides Acid anhydrides acids 10.4 Conditions to avoid Strong heating. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - > 2.000 mg/kg Remarks: (External MSDS) Symptoms: Possible damages:, mucosal irritations Dermal: No data available Skin corrosion/irritation Skin - Rabbit Result: irritating (OECD Test Guideline 404) Serious eye damage/eye irritation Eyes - Rabbit Result: Eye irritation (OECD Test Guideline 405) Respiratory or skin sensitization No data available Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: RG8225000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Under given conditions, contact with nitrites or nitric acid can lead to the formation of nitrosamines, which have shown themselves to be carcinogenic in animal experiments. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.
ECOLOGICAL INFORMATION	12.1 Toxicity No data available Toxicity to algae EC50 - Desmodesmus subspicatus (green algae) - 1,31 mg/l - 72 h (DIN 38412) Remarks: (above the solubility limit in the test medium) (trioctylamine, n-) EC50 - Desmodesmus subspicatus (green algae) - 1,31 mg/l - 72 h (DIN 38412) Remarks: (above the solubility limit in the test medium) (trioctylamine, n-) 12.2 Persistence and degradability Biodegradability Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301F) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 3082 IMDG: 3082 IATA: 3082 14.2 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (trioctylamine, n-) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (trioctylamine, n-) IATA: Environmentally hazardous substance, liquid, n.o.s. (trioctylamine, n-) 14.3 Transport hazard class(es) ADR/RID: 9 IMDG: 9 IATA: 9 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: yes 14.6 Special precautions for user Tunnel restriction code : (-) Further information Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ENVIRONMENTAL HAZARDS Other regulations Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!

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Trioctylamine