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Benzyl butyl phthalate

Item number678979
CAS85-68-7
FormulaC19H20O4
Molecular weight312,36 g/mol
Quantity 1x250mg
storage conditions20 °C
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Benzyl butyl phthalate

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 03.12.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Benzyl butyl phthalate
Catalog No.:678979
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Reproductive toxicity (Category 1B), H360Df
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC
R61
R62
N Dangerous for the
environment
R50/53
Label elements
PictogramGHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H360Df May damage the unborn child. Suspected of damaging fertility.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P273 Avoid release to the environment.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard
Statements
none
Restricted to professional users.
2.3 Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C19H20O4
Molecular Weight : 312,36 g/mol
CAS-No. : 85-68-7
EC-No. : 201-622-7
Index-No. : 607-430-00-3
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Benzyl butyl phthalate Included in the Candidate List of Substances of Very High Concern (SVHC)
according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
Index-No.
85-68-7
201-622-7
607-430-00-3
Repr. 1B; Aquatic Acute 1;
Aquatic Chronic 1; H360Df,
H410
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Benzyl butyl phthalate Included in the Candidate List of Substances of Very High Concern (SVHC)
according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
Index-No.
85-68-7
201-622-7
607-430-00-3
T, N, Repr.Cat.2, Repr.Cat.3,
R61 - R62 - R50/53
<= 100 %
FormulaC19H20O4
Molecular Weight (g/mol)312.36
CAS-No.85-68-7
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
no data available
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid exposure - obtain special instructions before use.Avoid inhalation of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry Hands Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: colourless
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing
point
Melting point/freezing point: < -35 °C
f) Initial boiling point and
boiling range
370 °C g) Flash point 113,0 °C - closed cup
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower
flammability or
explosive limits
no data available
k) Vapour pressure 19,2 hPa at 250,0 °C
0,3 hPa at 150,0 °C
l) Vapour density no data available
m) Relative density 1,1 g/cm3 at 25 °C
n) Water solubility 0,00269 g/l at 25 °C - OECD Test Guideline 105 - slightly soluble
o) Partition coefficient: noctanol/
water
log Pow: 4,91 at 20 °C
p) Auto-ignition
temperature
232,0 °C
q) Decomposition
temperature
no data available
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
9.2 Other safety information
no data available
STABILITY AND REACTIVITY10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents, Strong bases
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - rat - male and female - 2.330 mg/kg
(OECD Test Guideline 401)
LD50 Dermal - rabbit - > 10.000 mg/kg
Skin corrosion/irritation
no data available Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
- guinea pig
Result: Does not cause skin sensitisation.
Germ cell mutagenicity
Ames test
S. typhimurium
Result: negative
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC, ACGIH, NTP, or EPA classification.
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Benzyl butyl phthalate)
Reproductive toxicity
Presumed human reproductive toxicant
Overexposure may cause reproductive disorder(s) based on tests with laboratory animals.
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
Repeated dose toxicity - rat - male - Oral - No observed adverse effect level - 550 mg/kg
RTECS: TH9990000
May cause endocrine disruption.
pancreas -
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Lepomis macrochirus (Bluegill) - 1,7 mg/l - 96,0 h
NOEC - Oncorhynchus mykiss (rainbow trout) - 0,48 mg/l - 96,0 h
flow-through test LC50 - Pimephales promelas (fathead minnow) - 2,1 mg/l -
96 h
(OECD Test Guideline 203)
Toxicity to daphnia and
other aquatic
invertebrates
static test LC50 - Daphnia magna (Water flea) - 1,8 mg/l - 48 h
Toxicity to algae Growth inhibition EC50 - Desmodesmus subspicatus (green algae) - 0,31 mg/l
- 72 h
(OECD Test Guideline 201)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 14 d
Result: 81 % - Readily biodegradable.
12.3 Bioaccumulative potential
Bioaccumulation Lepomis macrochirus (Bluegill) - 21 d
- 0,00973 mg/l Bioconcentration factor (BCF): 663
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects.
Avoid release to the environment
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3082 IMDG: 3082 IATA: 3082
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Benzyl butyl phthalate)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Benzyl butyl phthalate)
IATA: Environmentally hazardous substance, liquid, n.o.s. (Benzyl butyl phthalate)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
14.6 Special precautions for user
no data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Authorisations and/or restrictions on use
Benzyl butyl phthalate CAS-No.: 85-68-7
EU. REACH - Annex XIV: List of substances subject to authorisation
Toxic for reproduction (category 1B)
Sunset Date: 21.02.2015
Exempted (Categories of) Uses: Uses in the immediate packaging of medicinal products covered under
Regulation (EC) No 726/2004, Directive 2001/82/EC, and/or Directive 2001/83/EC.
Benzyl butyl phthalate CAS-No.: 85-68-7
Candidate List of Substances of Very High Concern for Authorisation
Toxic for reproduction (article 57c)
ED/67/2008
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!