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Nonylphenol (technical)

Item number677201
CAS84852-15-3
FormulaC15H24O
Molecular weight220,35 g/mol
Quantity 1x250mg
storage conditions20 °C
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Nonylphenol (technical)

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 03.12.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Nonylphenol (technical)
Catalog No.:677201
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Skin corrosion (Category 1B), H314
Reproductive toxicity (Category 2), H361fd
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC
R62, R63
C Corrosive R34
Xn Harmful R22
N Dangerous for the
environment
R50/53
Label elements
PictogramGHS05 acid
acid
GHS07 exclam
exclam
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C15H24O
Molecular weight : 220,35 g/mol
CAS-No. : 84852-15-3
EC-No. : 284-325-5
Index-No. : 601-053-00-8
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
4-Nonylphenol, branched Included in the Candidate List of Substances of Very High Concern (SVHC)
according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
Index-No.
84852-15-3
284-325-5
601-053-00-8
Acute Tox. 4; Skin Corr. 1B;
Repr. 2; Aquatic Acute 1;
Aquatic Chronic 1; H302,
H314, H361fd, H410
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
4-Nonylphenol, branched Included in the Candidate List of Substances of Very High Concern (SVHC)
according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
Index-No.
84852-15-3
284-325-5
601-053-00-8
C, N, Repr.Cat.3, R22 - R34 -
R62 - R63 - R50/53
<= 100 %
FormulaC15H24O
Molecular Weight (g/mol)220.35
CAS-No.84852-15-3
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a
physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection
tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching gloves outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU). Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
No data available
f) Initial boiling point and
boiling range
302 °C at ca.1.010 hPa
g) Flash point 154 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure 0,01 hPa at 38 °C
l) Vapour density No data available
m) Relative density 0,937 g/cm3 at 25 °C
n) Water solubility ca.5,7 g/l at 25 °C - slightly soluble
o) Partition coefficient: noctanol/
water
log Pow: 5,4 at 23 °C
p) Auto-ignition
temperature
372 °C at 1.013,250 hPa
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available 10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - 1.412 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Causes burns. - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Corrosive - 72 h
(OECD Test Guideline 405)
Respiratory or skin sensitisation
Maximisation Test (GPMT) - Guinea pig
Result: Does not cause skin sensitisation.
(OECD Test Guideline 406)
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Suspected human reproductive toxicant
Reproductive toxicity - Rat - Oral
Effects on Newborn: Growth statistics (e.g., reduced weight gain). Effects on Newborn: Physical.
Specific target organ toxicity - single exposure
No data available Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
Repeated dose toxicity - Rat - male and female - No observed adverse effect level - 10 mg/kg - Lowest
observed adverse effect level - 50 mg/kg
RTECS: SM5650000
Cough, Shortness of breath, Headache, Nausea, Vomiting, To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish flow-through test LC50 - Lepomis macrochirus - 0,209 mg/l - 96 h
Toxicity to daphnia and
other aquatic
semi-static test EC50 - Daphnia magna (Water flea) - 0,0844 mg/l - 48 h invertebrates
Toxicity to algae static test EC50 - Selenastrum capricornutum (green algae) - 0,33 mg/l - 72 h
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 62 % - Readily biodegradable
(OECD Test Guideline 301F)
Remarks: The 10 day time window criterion is not fulfilled.
12.3 Bioaccumulative potential
Bioaccumulation Pimephales promelas (fathead minnow) - 28 d
Bioconcentration factor (BCF): 740
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3145 IMDG: 3145 IATA: 3145
14.2 UN proper shipping name
ADR/RID: ALKYLPHENOLS, LIQUID, N.O.S. (4-Nonylphenol, branched)
IMDG: ALKYLPHENOLS, LIQUID, N.O.S. (4-Nonylphenol, branched)
IATA: Alkylphenols, liquid, n.o.s.
14.3 Transport hazard class(es)
ADR/RID: 8 IMDG: 8 IATA: 8
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Authorisations and/or restrictions on use
4-Nonylphenol, branched CAS-No.: 84852-15-3
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
Equivalent level of concern having probable serious effects to the environment (article 57 f)
ED/169/2012
4-Nonylphenol, branched CAS-No.: 84852-15-3
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
4-Nonylphenol, branched CAS-No.: 84852-15-3
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
4-Nonylphenol, branched CAS-No.: 84852-15-3
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical qualifying for PIC notification.
4-Nonylphenol, branched CAS-No.: 84852-15-3
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical qualifying for PIC notification.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!