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Perfluorooctane sulfonamide

Item number676345
CAS754-91-6
FormulaC8H2F17NO2S
Molecular weight499,15 g/mol
Quantity 1X100MG
storage conditions20 °C
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Perfluorooctane sulfonamide

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 23.06.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Perfluorooctane sulfonamide
Catalog No.:676345
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Carcinogenicity (Category 2), H351
Reproductive toxicity (Category 1B), H360D
Effects on or via lactation, H362
Specific target organ toxicity - repeated exposure (Category 1), H372
Long-term (chronic) aquatic hazard (Category 2), H411
Label elements
PictogramGHS06 skull
skull
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Signal word Danger
Hazard statement(s)
H302 + H332 Harmful if swallowed or if inhaled.
H351 Suspected of causing cancer.
H360D May damage the unborn child.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P263 Avoid contact during pregnancy and while nursing.
P273 Avoid release to the environment.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental Hazard Statements
none

Reduced Labeling (<= 125 ml)

Signal word Danger

Hazard statement(s)
H351 Suspected of causing cancer.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs through prolonged or repeated exposure.
H360D May damage the unborn child.

Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental Hazard Statements
none

2.3 Other hazards

This substance/mixture contains components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB).
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances

Synonyms : Heptadecafluorooctanesulphonamide
Formula : C8H2F17NO2S
Molecular weight : 499,14 g/mol
CAS-No. : 754-91-6
EC-No. : 212-046-0
FormulaC8H2F17NO2S
Molecular Weight (g/mol)499.15
CAS-No.754-91-6
FIRST AID MEASURES4.1 Description of first-aid measures

General advice
Show this material safety data sheet to the doctor in attendance.

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media

Suitable extinguishing media
Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.

5.2 Special hazards arising from the substance or mixture

Nature of decomposition products not known.
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.

5.3 Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

5.4 Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the
danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area.
Avoid generation of dusts.

6.4 Reference to other sections

For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling

Advice on safe handling
Work under hood. Do not inhale substance/mixture.

Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.
For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions
Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons.

Storage class
Storage class (TRGS 510): 6.1C: Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters

Ingredients with workplace control parameters

8.2 Exposure controls

Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves

Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min

Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min

Body Protection
protective clothing

Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type P3

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties

a) Appearance Form: solid
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting point/freezing point
Melting point/range: 151 - 152 °C
f) Initial boiling point and boiling range
120 °C at 3 hPa
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Density No data available
Relative density No data available
n) Water solubility practically insoluble
o) Partition coefficient: n-octanol/water
log Pow: 8,19 at 25 °C - Potential bioaccumulation, (Lit.)
p) Autoignition temperature No data available
q) Decomposition temperature No data available
r) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
s) Explosive properties No data available
t) Oxidizing properties No data available

9.2 Other safety information

No data available
STABILITY AND REACTIVITY10.1 Reactivity

The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally
be assumed.

10.2 Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

no information available

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects

Acute toxicity
Acute toxicity estimate Oral - 500,1 mg/kg (Expert judgment)
Acute toxicity estimate Oral - 500,1 mg/kg (Expert judgment)
Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment)
Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment)
Dermal: No data available

Skin corrosion/irritation
No data available

Serious eye damage/eye irritation
Causes serious eye damage.

Respiratory or skin sensitization
No data available

Germ cell mutagenicity
No data available
No data available
No data available

Carcinogenicity
Suspected of causing cancer.

Reproductive toxicity
May damage the unborn child.
Studies indicating a hazard to babies during the lactation period

Specific target organ toxicity - single exposure
No data available

Specific target organ toxicity - repeated exposure
Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard
No data available

11.2 Additional Information

Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
RTECS: RG9701400
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Handle in accordance with good industrial hygiene and safety practice.
ECOLOGICAL INFORMATION12.1 Toxicity

No data available
Toxicity to daphnia and other aquatic invertebrates
Remarks: No data available (Heptadecafluorooctanesulphonamide)
Toxicity to algae Remarks: No data available (Heptadecafluorooctanesulphonamide)

12.2 Persistence and degradability

No data available

12.3 Bioaccumulative potential

Accumulation in aquatic organisms is expected.

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB).

12.6 Endocrine disrupting properties

Product:
Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

Discharge into the environment must be avoided
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods

Product
Waste material must be disposed of in accordance with the national and local regulations.
Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
TRANSPORT INFORMATION14.1 UN number

ADR/RID: 3077 IMDG: 3077 IATA: 3077

14.2 UN proper shipping name

ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Heptadecafluorooctanesulphonamide)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Heptadecafluorooctanesulphonamide)
IATA: Environmentally hazardous substance, solid, n.o.s. (Heptadecafluorooctanesulphonamide)

14.3 Transport hazard class(es)

ADR/RID: 9 IMDG: 9 IATA: 9

14.4 Packaging group

ADR/RID: III IMDG: III IATA: III

14.5 Environmental hazards

ADR/RID: yes IMDG Marine pollutant: yes IATA: yes

14.6 Special precautions for user

Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

National legislation
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances: ENVIRONMENTAL HAZARDS

Other regulations
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.

15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!