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Tri-n-pentyltin chloride

Item number689967
CAS3342-67-4
FormulaC15H33ClSn
Molecular weight367,59 g/mol
Quantity 1x25mg
storage conditions20 °C

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 03.12.2022
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Tri-n-pentyltin chloride
Catalog No.:689967
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 3
H301
Skin corrosion/irritation, Category 2
H315
Serious eye damage/eye irritation, Category 2
H319
Full text of H statements : see section 1
Adverse physicochemical, human health and environmental effects
No additional information available
Label elements
PictogramGHS06 skull
skull
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP):
GHS06
Signal word (CLP):
Danger
Hazard statements (CLP):
H301 - Toxic if swallowed. H315 - Causes skin irritation. H319 - Causes serious eye irritation.
Precautionary statements (CLP):
P280 - Wear protective gloves/protective clothing/eye protection/face protection. P264 - Wash hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P301+P310 - IF SWALLOWED: Immediately call a doctor. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3. Other hazards
No additional information available
COMPOSITION/INFORMATION ON INGREDIENTS3.1. Substances
Substance type:
Multi-constituent
Name:
TRI-n-PENTYLCHLOROTIN, tech-95
CAS-No. :3342-67-4
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
Tripentyltin chloride
(CAS-No.) 3342-67-4
90 - 100
Acute Tox. 3 (Oral), H301
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Other Organotins
0 - 10
Not classified
Full text of H-statements: see section 16
FormulaC15H33ClSn
Molecular Weight (g/mol)367.59
CAS-No.3342-67-4
FIRST AID MEASURES4.1. Description of first aid measures
First-aid measures general: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label.
First-aid measures after inhalation: Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical advice.
First-aid measures after skin contact: Wash with plenty of water/…. Get medical advice/attention.
First-aid measures after eye contact: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion: Never give anything by mouth to an unconscious person. Get immediate medical advice/attention
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation: May cause irritation to the respiratory tract. Overexposure may cause: Cough. Headache. Nausea.
Symptoms/effects after skin contact: Causes skin irritation. Organotins may be absorbed through the skin.
Symptoms/effects after eye contact: Causes serious eye irritation.
Symptoms/effects after ingestion: Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
Note to physician: Application of corticosteroid creams has been effective in treating severe skin irritation. If blisters develop, they may require abrasion to promote healing
FIRE-FIGHTING MEASURES5.1. Extinguishing media
Suitable extinguishing media: Water spray. Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media: None known.
5.2. Special hazards arising from the substance or mixture
Fire hazard: Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame.
5.3. Advice for firefighters
Firefighting instructions: Use water spray to cool exposed surfaces. Exercise caution when fighting any chemical fire.
Protection during firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Avoid all eye and skin contact and do not breathe vapour and mist.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment: Wear protective equipment as described in Section 8.
Emergency procedures: Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up: Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
HANDLING AND STORAGE7.1. Precautions for safe handling
Precautions for safe handling: Avoid all eye and skin contact and do not breathe vapour and mist. Use only in well ventilated areas.
Hygiene measures: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions: Keep container tightly closed. Keep out of reach of children.
Incompatible materials: Bases. Direct sunlight. Reducing agents. Moisture.
Water :Storage area: Store in a well-ventilated place. Store away from heat.
7.3. Specific end use(s)
No additional information available
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Other Organotins
Italy - Portugal - USA ACGIH
ACGIH TWA (mg/m3)
0.1 mg/m3 as tin
USA OSHA
OSHA PEL (TWA) (mg/m3)
0.1 mg/m3 as tin
Tripentyltin chloride (3342-67-4)
Italy - Portugal - USA ACGIH
ACGIH TWA (mg/m3)
0.1 mg/m3 as tin
USA OSHA
OSHA PEL (TWA) (mg/m3)
0.1 mg/m3 as tin
8.2. Exposure controls
Appropriate engineering controls:
Provide local exhaust or general room ventilation.
Personal protective equipment:
Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Hand protection:
Neoprene or nitrile rubber gloves
Eye protection:
Chemical goggles. Contact lenses should not be worn
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified combination organic vapor/acid gas (yellow cartridge) respirator.
PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties
Physical state: Liquid
Appearance:Colorless liquid.
Molecular mass: 367.57 g/mol
Colour:Pale yellow.
Odour:characteristic.
Odour threshold:No data available
Refractive index:1.4
86pH:No data available
Relative evaporation rate (butylacetate=1):No data available
Melting point:No data available
Freezing point:< 0 °C
Boiling point:120 °C @ 0.25 mm Hg
Flash point:> 120 °C (TCC)
Auto-ignition temperature:No data available
Decomposition temperature:No data available
Flammability (solid, gas):No data available
Vapour pressure:25 mm Hg @ 170°C
Relative vapour density at 20 °C:No data available
Relative density:1.137
Solubility:Insoluble in water.
Log Pow:No data available
Log Kow:No data available
Viscosity, kinematic:4 cSt
Viscosity, dynamic:No data available
Explosive properties:No data available
Oxidising properties:No data available
Explosive limits:No data available
9.2. Other information
No additional information available
STABILITY AND REACTIVITY10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Direct sunlight causes slow degradation to an inorganic tin salt.
10.4. Conditions to avoid
Heat. Open flame. Sparks.
10.5. Incompatible materials
Bases. Direct sunlight. Reducing agents. Moisture. Water :
10.6. Hazardous decomposition products
Organic acid vapors. Tin oxides.
TOXICOLOGICAL INFORMATIONAcute toxicity:
Toxic if swallowed.
Tripentyltin chloride (3342-67-4)
LD50 oral rat
> 150 mg/kg
ATE CLP (oral)
100 mg/kg bodyweight
Skin corrosion/irritation:Causes skin irritation.
Serious eye damage/irritation:Causes serious eye irritation.
Respiratory or skin sensitisation:Not classified
Germ cell mutagenicity:Not classified
Carcinogenicity:Not classified
Reproductive toxicity:Not classified
STOT-single exposure:Not classified
STOT-repeated exposure:Not classified
Aspiration hazard:Not classified
Symptoms/effects after inhalation:May cause irritation to the respiratory tract. Overexposure may cause: Cough. Headache. Nausea.
Symptoms/effects after skin contact:Causes skin irritation. Organotins may be absorbed through the skin.
Symptoms/effects after eye contact:Causes serious eye irritation.
Symptoms/effects after ingestion:Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard.
Reason for classification:Expert judgment
ECOLOGICAL INFORMATION12.1. Toxicity
Ecology - general:
This material is acutely toxic to aquatic life if released to open waters. This material is toxic to wildlife and fish.
Acute aquatic toxicity:
Not classified
Chronic aquatic toxicity:
Not classified
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Product/Packaging disposal recommendations:Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility.
Ecology - waste materials:Avoid release to the environment.
TRANSPORT INFORMATION14.1. UN number
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR)
:
2788
UN-No. (IMDG)
:
2788
UN-No. (IATA)
:
2788
UN-No. (ADN)
:
2788
UN-No. (RID)
:
2788
14.2. UN proper shipping name
Proper Shipping Name (ADR)
:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Proper Shipping Name (IMDG)
:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Proper Shipping Name (IATA)
:
Organotin compound, liquid, n.o.s.
Proper Shipping Name (ADN)
:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Proper Shipping Name (RID)
:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Transport document description (ADR)
:
UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II, (D/E)
Transport document description (IMDG)
:
UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II, MARINE POLLUTANT
Transport document description (IATA)
:
UN 2788 Organotin compound, liquid, n.o.s. (TRI-n-PENTYLCHLOROTIN), 6.1, II
Transport document description (ADN)
:
UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II
Transport document description (RID)
:
UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR)
:
6.1
Danger labels (ADR)
:
6.1
:
IMDG
Transport hazard class(es) (IMDG)
:
6.1
Danger labels (IMDG)
:
6.1
IATA
Transport hazard class(es) (IATA)
:
6.1
Hazard labels (IATA)
:
6.1
ADN
Transport hazard class(es) (ADN)
:
6.1
Danger labels (ADN)
:
6.1
RID
Transport hazard class(es) (RID)
:
6.1
Danger labels (RID)
:
6.1
14.4. Packing group
Packing group (ADR)
:
II
Packing group (IMDG)
:
II
Packing group (IATA)
:
II
Packing group (ADN)
:
II
Packing group (RID)
:
II
14.5. Environmental hazards
Dangerous for the environment
:
No
Marine pollutant
:
Yes (IMDG only)
Other information
:
No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR)
:
T3
Special provisions (ADR)
:
43, 274
Limited quantities (ADR)
:
100ml
Excepted quantities (ADR)
:
E4
Packing instructions (ADR)
:
P001, IBC02
Mixed packing provisions (ADR)
:
MP15
Portable tank and bulk container instructions (ADR)
:
T11
Portable tank and bulk container special provisions (ADR)
:
TP2, TP27
Tank code (ADR)
:
L4BH
Tank special provisions (ADR)
:
TU15, TE19
Vehicle for tank carriage
:
AT Transport category (ADR):2
Special provisions for carriage - Loading, unloading and handling (ADR):CV13, CV28
Special provisions for carriage - Operation (ADR):S9, S19
Hazard identification number (Kemler No.):60
Orange plates:Tunnel restriction code (ADR):D/E
EAC code:2X
APP code:B
- Transport by sea
Special provisions (IMDG):43, 274
Limited quantities (IMDG):100 ml
Excepted quantities (IMDG):E4
Packing instructions (IMDG):P001
IBC packing instructions (IMDG):IBC02
Tank instructions (IMDG):T11
Tank special provisions (IMDG):TP2, TP13, TP27
EmS-No. (Fire):F-A
EmS-No. (Spillage):S-A
Stowage category (IMDG):A
Stowage and handling (IMDG):SW2
Properties and observations (IMDG):A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation.
- Air transport
PCA Excepted quantities (IATA):E4
PCA Limited quantities (IATA):Y641
PCA limited quantity max net quantity (IATA):1L
PCA packing instructions (IATA):654
PCA max net quantity (IATA):5L
CAO packing instructions (IATA):661
CAO max net quantity (IATA):60L
Special provisions (IATA):A3, A4, A6
ERG code (IATA):6L
- Inland waterway transport
Classification code (ADN):T3
Special provisions (ADN):43, 274, 802
Limited quantities (ADN):100 ml
Excepted quantities (ADN):E4
Equipment required (ADN):PP, EP, TOX, A
Ventilation (ADN):VE02
Number of blue cones/lights (ADN):2-
Rail transport
Classification code (RID):T3
Special provisions (RID):43, 274
Limited quantities (RID):100ml
Excepted quantities (RID):E4
Packing instructions (RID):P001, IBC02
Mixed packing provisions (RID):MP15
Portable tank and bulk container instructions (RID):T11
Portable tank and bulk container special provisions (RID):TP2, TP27
Tank codes for RID tanks (RID):L4BH
Special provisions for RID tanks (RID):TU15
Transport category (RID):2
Special provisions for carriage - Loading, unloading and handling (RID):CW13, CW28, CW31
Colis express (express parcels) (RID):CE5
Hazard identification number (RID):60
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
TRI-n-PENTYLCHLOROTIN, tech-95 is not on the REACH Candidate List
TRI-n-PENTYLCHLOROTIN, tech-95 is not on the REACH Annex XIV List
TRI-n-PENTYLCHLOROTIN, tech-95 is not subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012 concerning the export and import of hazardous chemicals.
TRI-n-PENTYLCHLOROTIN, tech-95 is not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic pollutants and amending Directive 79/117/EEC
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV:
Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen:
The substance is not listed
SZW-lijst van mutagene stoffen:
The substance is not listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding:
The substance is not listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid:
The substance is not listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling:
The substance is not listed
Denmark
Danish National Regulations:
Young people below the age of 18 years are not allowed to use the product
15.2. Chemical safety assessment
No additional information available
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!