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D3-Prosulfuron

Item number689956
FormulaC15H13D3F3N5O4S
Molecular weight422,40 g/mol
Quantity 1x5mg
storage conditions20 °C
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D3-Prosulfuron

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 30.01.2023
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:D3-Prosulfuron
Catalog No.:689956
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
environment
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Label elements
PictogramGHS07 exclam
exclam
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Signal word Warning
· Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
H410 Very toxic to aquatic life with long lasting effects.
· Precautionary statements
P264 Wash thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves / protective clothing.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P321 Specific treatment (see on this label).
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
· CAS No. Description
94125-34-5 prosulfuron
· Identification number(s) None
· EC number: 619-000-2
· Index number: 016-084-00-7
· RTECS: DB2925200
FormulaC15H13D3F3N5O4S
Molecular Weight (g/mol)422.40
CAS-No.
FIRST AID MEASURES4.1 Description of first aid measures
· General information:
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Seek medical treatment.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:
Rinse mouth. Do not induce vomiting.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
FIRE-FIGHTING MEASURES5.1 Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing.
6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up: Pick up mechanically.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
HANDLING AND STORAGE
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Lists used were valid at the time of SDS preparation.
8.2 Exposure controls
· Appropriate engineering controls No further data; see item 7.
· Individual protection measures, such as personal protective equipment
· General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Not required.
Use suitable respiratory protective device in case of insufficient ventilation.
· Hand protection
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves
Butyl rubber, BR
Fluorocarbon rubber (Viton)
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye/face protection Safety glasses
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
· General Information
· Physical state Solid
· Colour: Beige
· Odour: Odourless
· Odour threshold: Not determined.
· Melting point/freezing point: 155 °C
· Boiling point or initial boiling point and boiling
range Not determined.
· Flammability Not determined.
· Lower and upper explosion limit
· Lower: Not determined.
· Upper: Not determined.
· Flash point: Not applicable.
· Auto-ignition temperature: Not determined.
· Decomposition temperature: Not determined.
· pH Not applicable.
· Viscosity:
· Kinematic viscosity Not applicable.
· Dynamic: Not applicable.
· Solubility Acetone, Toluene, Ethyl Acetate, Ethanol
· water at 20 °C: 4 g/l
· Partition coefficient n-octanol/water (log value) 1.5 LogP
· Vapour pressure: Not applicable.
· Density and/or relative density
· Density: Not determined.
· Relative density Not determined.
· Vapour density Not applicable.
9.2 Other information
· Appearance:
· Form: Solid
· Important information on protection of health and
environment, and on safety.
· Ignition temperature: Not determined
· Explosive properties: Not determined.
· Change in condition
· Evaporation rate Not applicable.
· Information with regard to physical hazard classes
· Explosives Not applicable
Not applicable
· Flammable gases Not applicable
Not applicable
· Aerosols Not applicable
Not applicable
· Oxidising gases Not applicable
Not applicable
· Gases under pressure Not applicable
Not applicable
· Flammable liquids Not applicable
Not applicable
· Flammable solids Not applicable
Not applicable
· Self-reactive substances and mixtures Not applicable
Not applicable
· Pyrophoric liquids Not applicable
Not applicable
· Pyrophoric solids Not applicable
Not applicable
· Self-heating substances and mixtures Not applicable
Not applicable
· Substances and mixtures, which emit flammable
gases in contact with water Not applicable
Not applicable
· Oxidising liquids Not applicable
Not applicable
· Oxidising solids Not applicable
Not applicable
· Organic peroxides Not applicable
Not applicable
· Corrosive to metals Not applicable
Not applicable
· Desensitised explosives Not applicable
Not applicable
STABILITY AND REACTIVITY10.1 Reactivity
Stable under normal conditions.
No further relevant information available.
10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:
Formation of toxic gases is possible during heating or in case of fire.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid Heat.
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products:
Formation of toxic gases is possible during heating or in case of fire.
TOXICOLOGICAL INFORMATION11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
· Acute toxicity Harmful if swallowed or in contact with skin.
· LD/LC50 values relevant for classification:
Oral LD50 546 mg/kg (rat)
Dermal LD50 2,000 mg/kg (rat)
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
11.2 Information on other hazards
· Endocrine disrupting properties Substance is not listed.
ECOLOGICAL INFORMATION12.1 Toxicity
· Aquatic toxicity:
EC50/48 h >120 mg/l (daphnia)
EC50/72h 0.0089 mg/l (Algae)
LC50/96 h 155 mg/l (fish)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
12.6 Endocrine disrupting properties
The product does not contain substances with endocrine disrupting properties.
12.7 Other adverse effects
· Remark: Very toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Dispose of in accordance with national regulations.
TRANSPORT INFORMATION14.1 UN number or ID number
· ADR, IMDG, IATA UN3077
· ADR 3 0 7 7 E N V I R ONME NT A L L Y HA Z A RDO US
SUBSTANCE, SOLID, N.O.S. (prosulfuron)
· IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (prosulfuron), MARINE POLLUTANT
· IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S. (prosulfuron)
14.3 Transport hazard class(es)
· ADR, IMDG, IATA
· Class 9 Miscellaneous dangerous substances and articles.
· Label 9
14.4 Packing group
· ADR, IMDG, IATA III
14.5 Environmental hazards:
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· Special marking (IATA): Symbol (fish and tree)
14.6 Special precautions for user Warning: Miscellaneous dangerous substances and
articles.
· Hazard identification number (Kemler code): 90
· EMS Number: F-A,S-F
· Stowage Category A
· Stowage Code SW23 When transported in BK3 bulk container, see
7.6.2.12 and 7.7.3.9.
14.7 Maritime transport in bulk according to IMO
instruments Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 5 kg
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
· Transport category 3
· Tunnel restriction code E
· UN "Model Regulation": UN 3077 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S. (PROSULFURON), 9, III
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I Substance is not listed.
· Seveso category E1 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!