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D5-Leucomalachite green
| Item number | 676847 |
| CAS | 947601-82-3 |
| Formula | C23H21D5N2 |
| Molecular weight | 335,50 g/mol |
| Quantity | 1X10MG |
| storage conditions | 20 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS Show Safety Data Sheet online |
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| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 18.04.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | D5-Leucomalachite green |
| Catalog No.: | 676847 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Germ cell mutagenicity (Category 2), H341 Carcinogenicity (Category 2), H351 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16 |
| Label elements | |
| Pictogram | GHS07 exclam exclam GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Signal Word Warning Hazard statement(s) H302 Harmful if swallowed. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P202 Do not handle until all safety precautions have been read and understood. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Supplemental Hazard Statements none Reduced Labeling (<= 125 ml) Signal Word Warning Hazard statement(s) H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. Precautionary statement(s) P202 Do not handle until all safety precautions have been read and understood. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : Bis-(4-dimethylaminophenyl)phenyl-d5-methane, LMG-D5 Formula : C23H21D5N2 Molecular weight : 335,50 g/mol CAS-No. : 947601-82-3 EC-No. : 635-453-9 Classification : Acute Tox. 4; Muta. 2; Carc. 2; Aquatic Acute 1; Aquatic Chronic 1; H302, H341, H351, H400, H410 |
| Formula | C23H21D5N2 |
| Molecular Weight (g/mol) | 335.50 |
| CAS-No. | 947601-82-3 |
| FIRST AID MEASURES | 4.1 Description of first-aid measures General advice Show this material safety data sheet to the doctor in attendance. If inhaled After inhalation: fresh air. Call in physician. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. In case of eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Water Foam Carbon dioxide (CO2) Dry powder Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given 5.2 Special hazards arising from the substance or mixture Carbon oxides Nitrogen oxides (NOx) Combustible. Development of hazardous combustion gases or vapours possible in the event of fire. 5.3 Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. 5.4 Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Advice on safe handling Work under hood. Do not inhale substance/mixture. Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Tightly closed. Dry. Air and light sensitive. Storage class Storage class (TRGS 510): 11: Combustible Solids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves. Body Protection protective clothing Respiratory protection required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. Control of environmental exposure Do not let product enter drains. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Physical state solid b) Color No data available c) Odor No data available d) Melting point/freezing point No data available e) Initial boiling point and boiling range No data available f) Flammability (solid, gas) No data available g) Upper/lower flammability or explosive limits No data available h) Flash point Not applicable i) Autoignition temperature No data available j) Decomposition temperature No data available k) pH No data available l) Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: No data available m) Water solubility No data available n) Partition coefficient: n-octanol/water No data available o) Vapor pressure No data available p) Density No data available Relative density No data available q) Relative vapor density No data available r) Particle characteristics No data available s) Explosive properties No data available t) Oxidizing properties none 9.2 Other safety information No data available |
| STABILITY AND REACTIVITY | 10.1 Reactivity The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . 10.3 Possibility of hazardous reactions Violent reactions possible with: Strong oxidizing agents 10.4 Conditions to avoid no information available 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity Acute toxicity estimate Oral - 500,1 mg/kg (Expert judgment) Remarks: The value is given in analogy to the following substances: malachite green hydrochloride; [4-[α -[4-(dimethylamino)phenyl]benzylidene]cyclohexa-2,5-dien-1- ylidene]dimethylammonium chloride Inhalation: No data available Dermal: No data available Skin corrosion/irritation No data available Serious eye damage/eye irritation No data available Respiratory or skin sensitization No data available Germ cell mutagenicity Suspected of causing genetic defects. Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative Remarks: The value is given in analogy to the following substances: Leucomalachite green Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Result: negative Remarks: The value is given in analogy to the following substances: Leucomalachite green Test Type: comet assay Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Result: negative Remarks: The value is given in analogy to the following substances: Leucomalachite green Test Type: Transgenic rodent somatic cell gene mutation assay Species: Mouse Cell type: Liver cells Application Route: Oral Result: positive Remarks: The value is given in analogy to the following substances: Leucomalachite green Test Type: DNA binding study Species: Rat Cell type: Liver cells Application Route: Oral Result: positive Remarks: The value is given in analogy to the following substances: Leucomalachite green Carcinogenicity Suspected of causing cancer. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Ictalurus catus (catfish) - 0,14 mg/l - 96 h Remarks: The value is given in analogy to the following substances: Malachite green oxalate LC50 - Lepomis macrochirus (Bluegill sunfish) - 0,03 mg/l - 96 h Remarks: The value is given in analogy to the following substances: Malachite green Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 0,29 mg/l - 48 h Remarks: The value is given in analogy to the following substances: Malachite green oxalate 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects No data available |
| DISPOSAL CONSIDERATIONS | |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 3077 IMDG: 3077 IATA: 3077 14.2 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Leucomalachite Green-d5) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Leucomalachite Green-d5) IATA: Environmentally hazardous substance, solid, n.o.s. (Leucomalachite Green-d5) 14.3 Transport hazard class(es) ADR/RID: 9 IMDG: 9 IATA: 9 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: yes 14.6 Special precautions for user Tunnel restriction code : (-) Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids. Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9 |
| REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. Authorisations and/or restrictions on use National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances: ENVIRONMENTAL HAZARDS Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |